Fabrication and field testing of spiral-wound membrane modules for CO2 capture from flue gas

• Published in: Journal of membrane science Vol. 556; no. C; pp. 126 - 137
• Main Authors: Salim, Witopo, Vakharia, Varun, Chen, Yuanxin, Wu, Dongzhu, Han, Yang, Ho, W.S. Winston
• Format: Journal Article
• Language: English
• Published: United States Elsevier B.V 15-06-2018; Elsevier
• Subjects: Coal-fired flue gas; Engineering; Field test; Polymer Science; Post-combustion CO2 capture; Spiral-wound module; Spiral-wound module; Field test; Post-combustion CO2 capture; Coal-fired flue gas
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2018.04.001

A spiral-wound membrane module comprising face compression “O” rings for effective seal of gases was developed, including a spiral-wound membrane element, Plexiglas fiber-reinforced plastic tube, and membrane housing. The spiral-wound membrane modules demonstrated essentially no leakage. The concentration polarization phenomenon was observed at a dry feed gas flow rate of less than 1000 sccm before humidification. Hence, the performances of the spiral-wound membrane modules were evaluated using both dry feed and sweep gas flow rates each at 1000 sccm before humidification at the typical flue gas temperature of 57 °C. The feed and sweep gas pressures were at 1.5 and 1 psig, respectively. By using either a simulated flue gas or an actual flue gas, the spiral-wound membrane modules showed similar performance results with a CO2 permeance of greater than 800 GPU and a CO2/N2 selectivity of more than 140, which were essentially identical to the results obtained from the flat-sheet membrane used for the module fabrication and tested in laboratory with the simulated flue gas. The pressure drops of the modules were satisfactory, i.e., less than 1.5 psi/m. During the field test using the actual flue gas at the National Carbon Capture Center in Wilsonville, Alabama, the performances of the modules revealed some unexpected issues including the feed spacer indentations on the membrane selective layer and the leakage at glue lines. These issues were resolved by improving the spiral-wound membrane module fabrication using a smoother feed spacer and a longer glue curing time. The field test results of the modules have shown their good potential for the post-combustion CO2 capture from coal-fired power plants.
•A new spiral-wound membrane module with face compression “O” rings was fabricated.•Spiral-wound membrane modules were tested with both simulated and actual flue gas.•Concentration polarization phenomenon was observed at low feed-gas flow rates.•High performance was obtained with an acceptable pressure drop of <1.5 psi/m.•Field test result has shown the potential for CO2 capture in coal-fired power plants.