A screening method of uranyl extractants in H2SO4 solutions

• Published in: Tetrahedron letters Vol. 56; no. 2; pp. 308 - 311
• Main Authors: Pasquier, S., Vercouter, T., Taran, F., Lamouroux, C., Plancque, G., Berthet, J.-C.
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 08-01-2015; Elsevier
• Subjects: Chemical Sciences; Complexation; Coordination chemistry; Iron; Phosphonate; Screening; Selectivity; Uranium; Complexation; Screening; Iron; Selectivity; Uranium; Phosphonate
• ISSN: 0040-4039; 1873-3581
• DOI: 10.1016/j.tetlet.2014.11.068

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•Selective complexing agents of U(VI) are at the basis of uranium recovery processes.•A screening method was developed for identification of U(VI)-selective molecules.•Series of mono and bisphosphonate molecules were examined.•Their affinity for U(VI) and Fe(III) was assessed in acidic conditions by our method.•Two molecules out of fifty-one were found to be of potential interest.
A UV–Vis spectrophotometric and colorimetric screening method was developed for the selection of powerful and selective ligands for the uranyl ion in sulfuric acid media. The coordinating properties of a series of molecules (mono and bisphosphonate) toward UO22+ were examined through ligand displacement reactions observed by UV–visible from the {ArzH4–UO2}2− reference complex where Na2ArzH6 is a chromogenic molecule displaying a strong affinity for uranium. Uranium/iron selectivity was evaluated by recovering the screening data from two independent sets of experiments using two different chromogenic chelates: arsenazo III for uranium(VI) and BrPADAP for iron(III). As a result, two bisphosphonate ligands among a set of more than 50 phosphonate molecules were found to display a good affinity for UO22+ and relevant U/Fe selectivity at pH=2.1.