Nano-Crystalline Li1.2Mn0.6Ni0.2O2 Prepared via Amorphous Complex Precursor and Its Electrochemical Performances as Cathode Material for Lithium-Ion Batteries

• Published in: Materials Vol. 9; no. 8; p. 661
• Main Authors: He, Xiangming, Wang, Jixian, Wang, Li, Li, Jianjun
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 05-08-2016; MDPI
• Subjects: amorphous complex; Amorphous materials; Cations; Chelating agents; Composite materials; Crystal structure; Current density; Electric vehicles; Electrons; Li-rich oxide; Lithium; Lithium ion batteries; Microscopy; Morphology; Nanoparticles; Nanostructure; Particle size; Precursors; rate capability; Scanning electron microscopy; Temperature; Transmission electron microscopy; Beijing China; China
• ISSN: 1996-1944; 1996-1944
• DOI: 10.3390/ma9080661

An amorphous complex precursor with uniform Mn/Ni cation distribution is attempted for preparing a nano-structured layered Li-rich oxide (Li1.2Mn0.6Ni0.2O2)cathode material, using diethylenetriaminepentaacetic acid (DTPA) as a chelating agent. The materials are characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and electrochemical tests. The crystal structure of Li-rich materials is found to be closely related to synthesis temperature. As-obtained nano materials sintered at 850 °C for 10 h show an average size of 200 nm with a single crystal phase and good crystallinity. At a current density of 20 mA*g-1, the specific discharge capacity reaches 221 mAh*g-1 for the first cycle and the capacity retention is 81% over 50 cycles. Even at a current density of 1000 mA*g-1, the capacity is as high as 118 mAh*g-1. The enhanced rate capability can be ascribed to the nano-sized morphology and good crystal structure.