Cobalt doped TiO2: A stable and efficient photocatalyst for continuous hydrogen production from glycerol: Water mixtures under solar light irradiation

• Published in: International journal of hydrogen energy Vol. 38; no. 23; pp. 9655 - 9664
• Main Authors: Sadanandam, Gullapelli, Lalitha, Kannekanti, Kumari, Valluri Durga, Shankar, Muthukonda V., Subrahmanyam, Machiraju
• Format: Journal Article
• Language: English
• Published: Kidlington Elsevier Ltd 06-08-2013; Elsevier
• Subjects: Alternative fuels. Production and utilization; Applied sciences; Catalysis; Catalysts; Cobalt; Cobalt doped TiO2; Energy; Exact sciences and technology; Fuels; Glycerol: water mixtures; Glycerols; Hydrogen; Hydrogen production; Irradiation; Photocatalysis; Solar light; Titanium dioxide; Solar light; Cobalt doped TiO2; Hydrogen production; Glycerol: water mixtures; Hydrogen; Glycerol; Titanium oxide; Cobalt; Cobalt doped TiO
• ISSN: 0360-3199; 1879-3487
• DOI: 10.1016/j.ijhydene.2013.05.116

Glycerol is the main by-product during the trans-esterification of vegetable oils to biodiesel. In this study, we investigate the process of photocatalytic hydrogen production from glycerol aqueous solution, with the use of cobalt doped TiO2 photocatalyst under solar light irradiation. Cobalt doped TiO2 photocatalysts are prepared by impregnation method and these catalysts are characterized by XRD, EDAX, DRS, TEM, EPR and XPS techniques. DRS studies clearly show the expanded photo response of TiO2 into visible region on impregnation of Co2+ ions on surface of TiO2. XPS studies also show change in the binding energy values of O1s, Ti 2p and Co 2p, indicating that Co2+ ions are in interaction with TiO2. Maximum hydrogen production of 220 μ mol h−1 g−1 is observed on 2 wt% cobalt doped TiO2 catalysts in pure water under solar irradiation. A significant improvement in hydrogen production is observed in glycerol: water mixtures; and maximum hydrogen production of 11,021 μ mol h−1 g−1 is obtained over 1 wt% cobalt doped TiO2 in 5% glycerol aqueous solutions. Furthermore, to evaluate some reaction parameters such as cobalt wt% on TiO2, glycerol concentration, substrate effect (alcohols) and pH of the solution on the hydrogen production activity are systematically investigated. When the catalysts are examined under UV irradiation, a 3–4 fold increase in activity is observed where this activity seems to decrease with time; however, a continuous activity is observed under solar irradiation on these catalysts. The decreased activity could be ascribed the loss of cobalt ions under UV irradiation, as evidenced by EDAX and TEM analysis. A possible explanation for the stable and continuous activity of cobalt doped TiO2 photocatalysts under solar irradiation is proposed.
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•Cobalt doped TiO2 is found to be a highly active photocatalyst in visible region.•Maximum H2 production activity was observed on 1 wt% cobalt doped TiO2.•Continuous H2 production activity is achieved under solar light irradiation.•Optimized conditions are developed for maximum H2 production under solar light.