An Overview and Future Perspectives of Rechargeable Zinc Batteries

• Published in: Small (Weinheim an der Bergstrasse, Germany) Vol. 16; no. 23; pp. e2000730 - n/a
• Main Authors: Shi, Yuchuan, Chen, Ye, Shi, Lei, Wang, Ke, Wang, Biao, Li, Long, Ma, Yaming, Li, Yuhan, Sun, Zehui, Ali, Wajid, Ding, Shujiang
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01-06-2020
• Subjects: aqueous zinc batteries; cathode materials; Commercialization; Dendritic structure; Electrode materials; Electrodes; Energy storage; Lithium; Nanotechnology; Rechargeable batteries; Storage batteries; Zinc; zinc anodes; Zn2+ storage mechanisms; cathode materials; Zn2+ storage mechanisms; aqueous zinc batteries; zinc anodes
• ISSN: 1613-6810; 1613-6829
• DOI: 10.1002/smll.202000730

Aqueous rechargeable zinc‐based batteries have sparked a lot of enthusiasm in the energy storage field recently due to their inherent safety, low cost, and environmental friendliness. Although remarkable progress has been made in the exploration of performance so far, there are still many challenges such as low working voltage and dissolution of electrode materials at the material and system level. Herein, the central tenet is to establish a systematic summary for the construction and mechanism of different aqueous zinc‐based batteries. Details for three major zinc‐based battery systems, including alkaline rechargeable Zn‐based batteries (ARZBs), aqueous Zn ion batteries (AZIBs), and dual‐ion hybrid Zn batteries (DHZBs) are given. First, the electrode materials and energy storage mechanism of the three types of zinc‐based batteries are discussed to provide universal guidance for these batteries. Then, the electrode behavior of zinc anodes and strategies to deal with problems such as dendrite and passivation are recommended. Finally, some challenge‐oriented solutions are provided to facilitate the next development of zinc‐based batteries. Combining the characteristics of zinc‐based batteries with good use of concepts and ideas from other disciplines will surely pave the way for its commercialization.
Herein, a systematic summary for the construction and mechanism of different aqueous zinc‐based batteries is established. Details for three major zinc‐based battery systems, including alkaline rechargeable Zn‐based batteries, aqueous Zn ion batteries, and dual‐ion hybrid Zn batteries are given. Combining the characteristics of zinc‐based batteries with good use of concepts and ideas from other disciplines will surely pave the way for its commercialization.