Recent Advances in the Application of Selectfluor as a “Fluorine‐free” Functional Reagent in Organic Synthesis
Selectfluor, [1‐chloromethyl‐4‐fluoro‐1,4‐diazoniabicyclo‐[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but also a facile and efficient “fluorine‐free” functional reagent in other organic reactions. In this Minireview, we will present a brief histor...
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| Published in: | Chemistry, an Asian journal Vol. 15; no. 6; pp. 729 - 741 |
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| Main Authors: | , , , , |
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| Language: | English |
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16-03-2020
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| Abstract | Selectfluor, [1‐chloromethyl‐4‐fluoro‐1,4‐diazoniabicyclo‐[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but also a facile and efficient “fluorine‐free” functional reagent in other organic reactions. In this Minireview, we will present a brief history of Selectfluor as a transition metal oxidant, fluorine cation and radical initiator in “fluorine‐free” functionalizations over the last five years.
Selectfluor as a “fluorine‐free” functional reagent in the application of various organic reactions as a transition‐metal oxidant, fluorine cation and radical initiator. |
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| AbstractList | Abstract
Selectfluor, [1‐chloromethyl‐4‐fluoro‐1,4‐diazoniabicyclo‐[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but also a facile and efficient “fluorine‐free” functional reagent in other organic reactions. In this Minireview, we will present a brief history of Selectfluor as a transition metal oxidant, fluorine cation and radical initiator in “fluorine‐free” functionalizations over the last five years. Selectfluor, [1‐chloromethyl‐4‐fluoro‐1,4‐diazoniabicyclo‐[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but also a facile and efficient “fluorine‐free” functional reagent in other organic reactions. In this Minireview, we will present a brief history of Selectfluor as a transition metal oxidant, fluorine cation and radical initiator in “fluorine‐free” functionalizations over the last five years. Selectfluor, [1‐chloromethyl‐4‐fluoro‐1,4‐diazoniabicyclo‐[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but also a facile and efficient “fluorine‐free” functional reagent in other organic reactions. In this Minireview, we will present a brief history of Selectfluor as a transition metal oxidant, fluorine cation and radical initiator in “fluorine‐free” functionalizations over the last five years. Selectfluor as a “fluorine‐free” functional reagent in the application of various organic reactions as a transition‐metal oxidant, fluorine cation and radical initiator. |
| Author | Ge, Haibo Mudassir, Syed M. Yang, Ke Ali, Ahmed I. M. Song, Mengjie |
| Author_xml | – sequence: 1 givenname: Ke surname: Yang fullname: Yang, Ke email: keyang@cczu.edu.cn organization: Indiana University Purdue University Indianapolis – sequence: 2 givenname: Mengjie surname: Song fullname: Song, Mengjie organization: Changzhou University – sequence: 3 givenname: Ahmed I. M. surname: Ali fullname: Ali, Ahmed I. M. organization: Texas Tech University – sequence: 4 givenname: Syed M. surname: Mudassir fullname: Mudassir, Syed M. organization: Indiana University Purdue University Indianapolis – sequence: 5 givenname: Haibo orcidid: 0000-0001-6727-4602 surname: Ge fullname: Ge, Haibo email: hage@ttu.edu, geh@iupui.edu organization: Texas Tech University |
| BackLink | https://www.ncbi.nlm.nih.gov/pubmed/32068956$$D View this record in MEDLINE/PubMed |
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| Copyright | 2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
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| Keywords | “fluorine-free” functional reagent electrophilic fluorinating reagent organic synthesis Selectfluor |
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| Snippet | Selectfluor, [1‐chloromethyl‐4‐fluoro‐1,4‐diazoniabicyclo‐[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but... Selectfluor, [1-chloromethyl-4-fluoro-1,4-diazoniabicyclo-[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating agent but... Abstract Selectfluor, [1‐chloromethyl‐4‐fluoro‐1,4‐diazoniabicyclo‐[2.2.2]octane bis(tetrafluoroborate)], is not only an important electrophilic fluorinating... |
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| SubjectTerms | Chemical reactions Chemistry electrophilic fluorinating reagent Fluorine organic synthesis Oxidizing agents Reagents Selectfluor Transition metals “fluorine-free” functional reagent |
| Title | Recent Advances in the Application of Selectfluor as a “Fluorine‐free” Functional Reagent in Organic Synthesis |
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