A New Strategy to Improve the Toughness of Epoxy Thermosets-By Introducing Poly(ether nitrile ketone)s Containing Phthalazinone Structures

A New Strategy to Improve the Toughness of Epoxy Thermosets-By Introducing Poly(ether nitrile ketone)s Containing Phthalazinone Structures

As high brittleness limits the application of all epoxy resins (EP), here, it can be modified by high-performance thermoplastic poly(ether nitrile ketone) containing phthalazinone structures (PPENK). Therefore, the influence of different PPENK contents on the mechanical, thermal, and low-temperature...

Full description

Saved in:
Bibliographic Details
Published in:Materials Vol. 16; no. 7; p. 2878
Main Authors: Guo, Hongjun, Wang, Bing, Fu, Xin, Li, Nan, Li, Guiyang, Zheng, Guodong, Wang, Zaiyu, Liu, Cheng, Chen, Yousi, Weng, Zhihuan, Zhang, Shouhai, Jian, Xigao
Format: Journal Article
Language:English
Published: Switzerland MDPI AG 04-04-2023
MDPI
Subjects:
Curing
epoxy resin
Epoxy resins
Flexural strength
Glass transition temperature
Heat resistance
Impact strength
Ketones
Low temperature
low-temperature properties
Mechanical properties
Mixtures
Nanoparticles
PPENK
Shear strength
Temperature
Thermal stability
toughness and strength
China
toughness and strength
epoxy resin
low-temperature properties
PPENK
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:As high brittleness limits the application of all epoxy resins (EP), here, it can be modified by high-performance thermoplastic poly(ether nitrile ketone) containing phthalazinone structures (PPENK). Therefore, the influence of different PPENK contents on the mechanical, thermal, and low-temperature properties of EP was comprehensively investigated in this paper. The binary blend of PPENK/EP exhibited excellent properties due to homogeneous mixing and good interaction. The presence of PPENK significantly improved the mechanical properties of EP, showing 131.0%, 14.2%, and 10.0% increases in impact, tensile, and flexural strength, respectively. Morphological studies revealed that the crack deflection and bridging in PPENK were the main toughening mechanism in the blend systems. In addition, the PPENK/EP blends showed excellent thermal and low-temperature properties (-183 °C). The glass transition temperatures of the PPENK/EP blends were enhanced by approximately 50 °C. The 15 phr of the PPENK/EP blends had a low-temperature flexural strength of up to 230 MPa, which was 46.5% higher than EP. Furthermore, all blends exhibited better thermal stability.
Bibliography:ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1996-1944
1996-1944
DOI:10.3390/ma16072878