Novel Alkoxide Cluster Topologies Featuring Rare Seesaw Geometry at Transition Metal Centers

Caution! Chemists playing: Novel clusters of the form [M2Li2Cl2(OR)4] featuring rare seesaw geometry at the transition metal centers were synthesized for M=CrCo. The use of sterically hindering alkoxide ligands, as well as the inclusion of lithium ions in the structures enforces this highly unusual...

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Bibliographic Details
Published in:	Chemistry : a European journal Vol. 19; no. 37; pp. 12225 - 12228
Main Authors:	Bellow, James A., Fang, Dong, Kovacevic, Natalija, Martin, Philip D., Shearer, Jason, Cisneros, G. Andrés, Groysman, Stanislav
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 09-09-2013 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Subjects:	Alkoxides Chemistry Chemists cluster compounds Clusters continuous symmetry measures Inclusions Ligands Lithium ions seesaw geometry Topology Transition metals continuous symmetry measures cluster compounds seesaw geometry transition metals alkoxides
Online Access:	Get full text
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Summary:	Caution! Chemists playing: Novel clusters of the form [M2Li2Cl2(OR)4] featuring rare seesaw geometry at the transition metal centers were synthesized for M=CrCo. The use of sterically hindering alkoxide ligands, as well as the inclusion of lithium ions in the structures enforces this highly unusual configuration.
Bibliography:	ArticleID:CHEM201302558 Wayne State University ark:/67375/WNG-6SH0B3QC-F istex:21DA7F6CEDA9186BEADC294FD4A9CFDC6F7B1339 ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 BNL-102919-2013-JA DE-AC02-98CH10886 USDOE SC OFFICE OF SCIENCE (SC)
ISSN:	0947-6539 1521-3765
DOI:	10.1002/chem.201302558