Iridium‐Catalyzed α‐Selective Arylation of Styrenes by Dual C−H Functionalization

An IrI‐system modified with a ferrocene derived bisphosphine ligand promotes α‐selective arylation of styrenes by dual C−H functionalization. These studies offer a regioisomeric alternative to the Pd‐catalyzed Fujiwara–Moritani reaction. A regioisomeric alternative to the Pd‐catalyzed Fujiwara–Morit...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 57; no. 43; pp. 14198 - 14202
Main Authors:	Cooper, Phillippa, Crisenza, Giacomo E. M., Feron, Lyman J., Bower, John F.
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 22-10-2018 John Wiley and Sons Inc
Edition:	International ed. in English
Subjects:	arylation Communication Communications C−H activation Iridium styrene Styrenes iridium C−H activation arylation styrene
Online Access:	Get full text
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Summary:	An IrI‐system modified with a ferrocene derived bisphosphine ligand promotes α‐selective arylation of styrenes by dual C−H functionalization. These studies offer a regioisomeric alternative to the Pd‐catalyzed Fujiwara–Moritani reaction. A regioisomeric alternative to the Pd‐catalyzed Fujiwara–Moritani reaction is presented. An IrI system modified with a ferrocene‐derived bisphosphine ligand promotes α‐selective arylation of styrenes by dual C−H functionalization.
Bibliography:	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	1433-7851 1521-3773 1521-3773
DOI:	10.1002/anie.201808299