Dichloridobis(1,3-diisopropyl-4,5-di-methyl-1H-imidazol-3-ium-2-thiol-ate-κS)copper(II)

The mol-ecular structure of the title compound, [CuCl2(C11H20N2S)2], shows the Cu(II) atom with a distorted tetra-hedral geometry from two Cl atoms [Cu-Cl = 2.2182 (6) Å] and two thione S atoms [Cu-S = 2.3199 (6) Å]. The angles at the copper cation, which lies on a twofold rotation axis, are Cl-Cu-C...

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Bibliographic Details
Published in:	Acta crystallographica. Section E, Structure reports online Vol. 69; no. Pt 4; p. m211
Main Authors:	Flörke, Ulrich, Ahmida, Aziza, Schröder, Jörg, Egold, Hans, Henkel, Gerald
Format:	Journal Article
Language:	English
Published:	United States International Union of Crystallography 01-04-2013
Subjects:	Metal-Organic Papers
Online Access:	Get full text
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Summary:	The mol-ecular structure of the title compound, [CuCl2(C11H20N2S)2], shows the Cu(II) atom with a distorted tetra-hedral geometry from two Cl atoms [Cu-Cl = 2.2182 (6) Å] and two thione S atoms [Cu-S = 2.3199 (6) Å]. The angles at the copper cation, which lies on a twofold rotation axis, are Cl-Cu-Cl = 142.84 (4)°, Cl-Cu-S = 94.80 (2) and 99.97 (2)°, and S-Cu-S = 132.46 (4)°. The planes of the two imidazolium rings make a dihedral angle of 76.92 (8)°.
Bibliography:	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	1600-5368 1600-5368
DOI:	10.1107/S1600536813006879