An Odorless, One-Pot Synthesis of Thioesters from Organic Halides, Thiourea and Benzoyl Chlorides in Water

An Odorless, One-Pot Synthesis of Thioesters from Organic Halides, Thiourea and Benzoyl Chlorides in Water

Thioesterification can be realized via an odorless, one‐pot reaction through the in situ generation of S‐alkylisothiouronium salts from organic halides and thiourea in aqueous Triton X‐100 (TX100) micelles. The protocol is free of foul‐smell thiols and organic solvents, and operates under mild condi...

Full description

Saved in:
Bibliographic Details
Published in:Advanced synthesis & catalysis Vol. 355; no. 7; pp. 1271 - 1276
Main Authors: Lu, Guo-ping, Cai, Chun
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 03-05-2013
WILEY‐VCH Verlag
Subjects:
Catalysis
green chemistry
micelles
multicomponent reactions
S-alkylisothiouronium salts
thioesterification
water chemistry
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Thioesterification can be realized via an odorless, one‐pot reaction through the in situ generation of S‐alkylisothiouronium salts from organic halides and thiourea in aqueous Triton X‐100 (TX100) micelles. The protocol is free of foul‐smell thiols and organic solvents, and operates under mild conditions, thereby offering considerable potential for applications in organic synthesis.
Bibliography:istex:77047239DA89A48FE8C35CE900D7717EA8D3CE93
China North Industries Coporation - No. NORINCO 00402040103
ArticleID:ADSC201201059
ark:/67375/WNG-VLT18ZGF-T
ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201201059