Ionic Conductivity and Cycling Stability Improvement of PVDF/Nano-Clay Using PVP as Polymer Electrolyte Membranes for LiFePO₄ Batteries

• Published in: Membranes (Basel) Vol. 8; no. 3; p. 36
• Main Authors: Dyartanti, Endah R, Purwanto, Agus, Widiasa, I Nyoman, Susanto, Heru
• Format: Journal Article
• Language: English
• Published: Switzerland MDPI 01-07-2018; MDPI AG
• Subjects: nano-clay; poly(vinylpyrrolidone); polymer electrolyte membranes; PVDF membranes; PVDF membranes; nano-clay; poly(vinylpyrrolidone); polymer electrolyte membranes
• ISSN: 2077-0375; 2077-0375
• DOI: 10.3390/membranes8030036

In this paper, we present the characteristics and performance of polymer electrolyte membranes (PEMs) based on poly(vinylidene fluoride) (PVDF). The membranes were prepared via a phase-inversion method (non-solvent-induced phase separation (NIPS)). As separators for lithium battery systems, additive modified montmorillonite (MMT) nano-clay served as a filler and poly(vinylpyrrolidone) (PVP) was used as a pore-forming agent. The membranes modified with an additive (8 wt % nano-clay and 7 wt % PVP) showed an increased porosity (87%) and an uptake of a large amount of electrolyte (801.69%), which generated a high level of ionic conductivity (5.61 mS cm
) at room temperature. A graphite/PEMs/LiFePO₄ coin cell CR2032 showed excellent stability in cycling performance (average discharge capacity 127 mA h g
). Based on these results, PEMs are promising materials to be used in Polymer Electrolyte Membranes in lithium-ion batteries.