Controlling spins in adsorbed molecules by a chemical switch

• Published in: Nature communications Vol. 1; no. 5; pp. 1 - 7
• Main Authors: Jung, Thomas A, Ballav, Nirmalya, Wäckerlin, Christian, Chylarecka, Dorota, Kleibert, Armin, Müller, Kathrin, Iacovita, Cristian, Nolting, Frithjof
• Format: Journal Article
• Language: English
• Published: London Nature Publishing Group UK 24-08-2010; Nature Publishing Group
• Subjects: 639/301/119/1001; 639/638/298/920; 639/638/440; Humanities and Social Sciences; multidisciplinary; Science; Science (multidisciplinary)
• ISSN: 2041-1723; 2041-1723
• DOI: 10.1038/ncomms1057

The development of chemical systems with switchable molecular spins could lead to the architecture of materials with controllable magnetic or spintronic properties. Here, we present conclusive evidence that the spin of an organometallic molecule coupled to a ferromagnetic substrate can be switched between magnetic
off
and
on
states by a chemical stimulus. This is achieved by nitric oxide (NO) functioning as an axial ligand of cobalt(II)tetraphenylporphyrin (CoTPP) ferromagnetically coupled to nickel thin-film (Ni(001)). On NO addition, the coordination sphere of Co
2+
is modified and a NO–CoTPP nitrosyl complex is formed, which corresponds to an
off
state of the Co spin. Thermal dissociation of NO from the nitrosyl complex restores the
on
state of the Co spin. The NO-induced reversible
off–on
switching of surface-adsorbed molecular spins observed here is attributed to a
spin trans
effect.
Chemical systems with switchable molecular spins could allow the development of materials with controllable spintronic properties. Here, the authors show that nitric oxide coordination to cobalt(II)tetraphenylporphyrin on a nickel surface, followed by thermal dissociation, leads to off-on spin switching.