Bromine-Mediated Cross-Dehydrogenative Coupling (CDC) Reactions

Significant advances in the development of CDC reactions have been made in recent years. However, metal-free CDC reaction remains comparatively under-developed. In view that a variety of readily available, cheap and environmentally friendly bromine reagents have been employed in bromination or oxida...

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Bibliographic Details
Published in:	Bulletin of the Chemical Society of Japan Vol. 91; no. 4; pp. 710 - 719
Main Authors:	Wang, Bin, Wong, Henry N C
Format:	Journal Article
Language:	English
Published:	Tokyo The Chemical Society of Japan 2018 Chemical Society of Japan
Subjects:	Bromination Bromine Chemical bonds Chemical synthesis Coupling Dehydrogenation Fascinating Molecules and Reactions Oxidation Reagents
Online Access:	Get full text
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Summary:	Significant advances in the development of CDC reactions have been made in recent years. However, metal-free CDC reaction remains comparatively under-developed. In view that a variety of readily available, cheap and environmentally friendly bromine reagents have been employed in bromination or oxidation in organic synthesis, we would like to summarize and discuss in this review examples of bromine-mediated CDC reactions, delineating significant and promising applications of these reagents in metal-free functionalization of C-H bonds.
ISSN:	0009-2673 1348-0634
DOI:	10.1246/bcsj.20170393