Effects of sonication on co-precipitation synthesis and activity of copper manganese oxide catalyst to remove methane and sulphur dioxide gases

• Published in: Ultrasonics sonochemistry Vol. 40; no. Pt A; pp. 57 - 67
• Main Authors: Yap, Yeow Hong, Lim, Mitchell S.W., Lee, Zheng Yee, Lai, Kar Chiew, Jamaal, Muhamad Ashraf, Wong, Farng Hui, Ng, Hoon Kiat, Lim, Siew Shee, Tiong, T. Joyce
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01-01-2018
• Subjects: Co-precipitation; Copper manganese oxide; Methane oxidation; Sonochemical synthesis; Ultrasound; Copper manganese oxide; Methane oxidation; Sonochemical synthesis; Ultrasound; Co-precipitation
• ISSN: 1350-4177; 1873-2828
• DOI: 10.1016/j.ultsonch.2017.06.032

•Higher ultrasonic intensity during synthesis improves overall catalyst performance.•Ultrasound treatment improves the specific surface area of the Cu-Mn oxide catalyst.•Ultrasound treatment improves the amorphicity of the Cu-Mn oxide catalyst.
The utilisation of ultrasound in chemical preparation has been the focus of intense study in various fields, including materials science and engineering. This paper presents a novel method of synthesising the copper-manganese oxide (Hopcalite) catalyst that is used for the removal of volatile organic compounds and greenhouse gases like carbon monoxide. Several samples prepared under different conditions, with and without ultrasound, were subjected to a series of characterisation tests such as XRD, BET, FE-SEM, EDX, TPR-H2, TGA and FT-IR in order to establish their chemical and physical properties. A series of catalytic tests using a micro-reactor were subsequently performed on the samples in order to substantiate the aforementioned properties by analysing their ability to oxidise compressed natural gas (CNG), containing methane and sulphur dioxide. Results showed that ultrasonic irradiation of the catalyst led to observable alterations in its morphology: surfaces of the particles were noticeably smoothed and an increased in amorphicity was detected. Furthermore, ultrasonic irradiation has shown to enhance the catalytic activity of Hopcalite, achieving a higher conversion of methane relative to non-sonicated samples. Varying the ultrasonic intensity also produced appreciable effects, whereby an increase in intensity results in a higher conversion rate. The catalyst sonicated at the highest intensity of 29.7W/cm2 has a methane conversion rate of 13.5% at 400°C, which was the highest among all the samples tested.