Possibility of Exciton Bose–Einstein Condensation in CdSe Nanoplatelets

• Published in: Nanomaterials (Basel, Switzerland) Vol. 13; no. 19; p. 2734
• Main Authors: Baghdasaryan, Davit A., Harutyunyan, Volodya A., Kazaryan, Eduard M., Sarkisyan, Hayk A., Petrosyan, Lyudvig S., Shahbazyan, Tigran V.
• Format: Journal Article
• Language: English
• Published: Basel MDPI AG 01-10-2023; MDPI
• Subjects: Analysis; Approximation; Bose-Einstein condensates; Bose-Einstein condensation; Cadmium selenide; Energy; Energy gap; Energy spectra; Excitation spectra; exciton states; Exciton theory; Excitons; Free electrons; Heat treating; Mathematical analysis; Nanocrystals; Nanoparticles; nanoplatelets; Platelets (materials); Quantum dots; Semiconductors; size quantization; Subsystems; Translational motion; Russia
• ISSN: 2079-4991; 2079-4991
• DOI: 10.3390/nano13192734

The quasi-two-dimensional exciton subsystem in CdSe nanoplatelets is considered. It is theoretically shown that Bose–Einstein condensation (BEC) of excitons is possible at a nonzero temperature in the approximation of an ideal Bose gas and in the presence of an “energy gap” between the ground and the first excited states of the two-dimensional exciton center of inertia of the translational motion. The condensation temperature (Tc) increases with the width of the “gap” between the ground and the first excited levels of size quantization. It is shown that when the screening effect of free electrons and holes on bound excitons is considered, the BEC temperature of the exciton subsystem increases as compared to the case where this effect is absent. The energy spectrum of the exciton condensate in a CdSe nanoplate is calculated within the framework of the weakly nonideal Bose gas approximation, considering the specifics of two-dimensional Born scattering.