An investigation of the role of plasma conditions on the deposition rate of electrochromic vanadium oxide thin films

• Published in: Journal of non-crystalline solids Vol. 351; no. 24; pp. 1987 - 1994
• Main Authors: Seman, Michael, Marino, Joey, Yang, Wenli, Wolden, Colin A.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01-08-2005; Elsevier
• Subjects: Amorphous semiconductors; glasses; Condensed matter: electronic structure, electrical, magnetic, and optical properties; Exact sciences and technology; Optical properties and condensed-matter spectroscopy and other interactions of matter with particles and radiation; Optical properties of specific thin films; Physics; 78.20.J; O110; E160; 66.30.D; E162; P260; 81.15.Gh; 78.66; Vanadium oxides; Growth rate; Ionic conductivity; Operating mode; Electrochromism; Deposition rate; Amorphous state; Thin films; Electro-optical effects; PECVD; Absorption spectra
• ISSN: 0022-3093; 1873-4812
• DOI: 10.1016/j.jnoncrysol.2005.05.016

Plasma-enhanced chemical vapor deposition (PECVD) has been used to form amorphous vanadium oxide thin films from mixtures of VOCl
3, O
2, and H
2. The deposition rate was examined as a function of PECVD operating conditions. Growth rates were found to be first order in VOCl
3, and independent of both O
2 and H
2. High quality vanadium oxide films were also deposited without the use of hydrogen. Rates were observed to increase with rf power, and decrease with operating pressure. Maximum rates were an order of magnitude greater than typically observed with physical vapor deposition techniques. Optical transmission and electrochemical analysis were used to quantify the electrochromic response. After initial cycling films demonstrated high transparency across the visible, and the optical band gap increased with lithium intercalation. Lithium ion diffusion coefficients approached 10
−11 cm
2/s, approximately an order of magnitude higher than literature values.