Fabrication of microporous layer - free hierarchical gas diffusion electrode as a low Pt-loading PEMFC cathode by direct growth of helical carbon nanofibers

• Published in: RSC advances Vol. 8; no. 72; pp. 41566 - 41574
• Main Authors: Sandström, Robin, Ekspong, Joakim, Annamalai, Alagappan, Sharifi, Tiva, Klechikov, Alexey, Wågberg, Thomas
• Format: Journal Article
• Language: English
• Published: England Royal Society of Chemistry 01-01-2018; The Royal Society of Chemistry
• Subjects: Carbon fibers; Catalysis; Catalysts; Charge transfer; Chemical vapor deposition; Chemistry; Diffusion layers; Electric contacts; Electric wire; Electrodes; Gaseous diffusion; Microfibers; Morphology; Nanofibers; Nanoparticles; Organic chemistry; Palladium; Platinum; Proton exchange membrane fuel cells; Spraying; Structural hierarchy
• ISSN: 2046-2069; 2046-2069
• DOI: 10.1039/c8ra07569g

Improving interfacial contact between each component in the proton exchange membrane fuel cell (PEMFC) can lead to a significant increase in power density and Pt utilization. In this work, the junction between the catalyst layer and gas diffusion layer (GDL) is greatly enhanced through direct attachment of helical carbon nanofibers, giving rise to a hierarchical structure within the electrical interconnections. The alternative novel GDL is produced by spraying a thin layer of Pd
C
precursor on commercial carbon paper, followed by chemical vapor deposition growth resulting in a surface morphology of well-attached nanofibers surrounding the microfibers present in the commercial carbon paper. Subsequent solvothermal deposition of platinum nanoparticles allowed evaluation of its suitability as gas diffusion electrode in cathodic H
/O
PEMFC environment. A combination of lowered charge transfer resistance and enhanced Pt-utilization is attributed to its unique wire-like appearance and its robust properties. The fabricated microporous layer - free GDL is suitable for relatively aggressive membrane electrode assembly fabrication procedures and is produced by industrially favorable techniques, rendering it capable of efficiently supporting small amounts of precious metal catalyst nanoparticles in various PEM applications.