Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

Crystal Structure of N,N-bis-(3-Carbomethoxy-5-methyl-pyrazol-1-ylmethyl)aniline

The tripodal ligand N,N-bis-(3-carbomethoxy-5-methylpyrazol-1-yl)methyl aniline (2) has been prepared by the condensation of aniline with two equivalents of N-hydroxymethyl[3-carbomethoxy-5-methyl]pyrazole. The molecule consists of two structurally analogous 3-carbomethoxy-5-methylpyrazol-1-ylmethyl...

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Bibliographic Details
Published in:Molecules (Basel, Switzerland) Vol. 7; no. 9; pp. 690 - 696
Main Authors: Daoudi, Maria, Larbi, Najib Ben, Benjelloun, Driss, Kerbal, Abdelali, Launay, Jean Pierre, Bonvoisin, Jacques, Jaud, Joël, Mimouni, Mostafa, Ben-Hadda, Taibi
Format: Journal Article
Language:English
Published: Basel MDPI AG 01-09-2002
MDPI
Subjects:
Chemical Sciences
Crystal structure
flexible ligand
Ligands
Metals
Molecular structure
Nitrogen
pyrazole
Radiation
Structure
tridentate
tripod
Morocco
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Summary:The tripodal ligand N,N-bis-(3-carbomethoxy-5-methylpyrazol-1-yl)methyl aniline (2) has been prepared by the condensation of aniline with two equivalents of N-hydroxymethyl[3-carbomethoxy-5-methyl]pyrazole. The molecule consists of two structurally analogous 3-carbomethoxy-5-methylpyrazol-1-ylmethyl moieties, which adopt a transoidal conformation via a central aniline ring, suggesting that this tripodal ligand is highly flexible and could accommodate many metals by coordination.
ISSN:1420-3049
1420-3049
DOI:10.3390/70900690