Hollow MXene Spheres and 3D Macroporous MXene Frameworks for Na‐Ion Storage

• Published in: Advanced materials (Weinheim) Vol. 29; no. 37
• Main Authors: Zhao, Meng‐Qiang, Xie, Xiuqiang, Ren, Chang E., Makaryan, Taron, Anasori, Babak, Wang, Guoxiu, Gogotsi, Yury
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01-10-2017
• Subjects: 3D frameworks; Biomedical materials; Catalysis; Electrochemical analysis; Energy consumption; Energy storage; Ethanol; Flakes; hollow spheres; Ion storage; Lithium sulfur batteries; Materials science; Metal carbides; MXene; MXenes; Na‐ion storage; Performance enhancement; Rechargeable batteries; Sodium-ion batteries; Storage batteries; templates; 3D frameworks; Na-ion storage; hollow spheres; MXene; templates
• ISSN: 0935-9648; 1521-4095
• DOI: 10.1002/adma.201702410

2D transition metal carbides and nitrides, named MXenes, are attracting increasing attentions and showing competitive performance in energy storage devices including electrochemical capacitors, lithium‐ and sodium‐ion batteries, and lithium–sulfur batteries. However, similar to other 2D materials, MXene nanosheets are inclined to stack together, limiting the device performance. In order to fully utilize MXenes' electrochemical energy storage capability, here, processing of 2D MXene flakes into hollow spheres and 3D architectures via a template method is reported. The MXene hollow spheres are stable and can be easily dispersed in solvents such as water and ethanol, demonstrating their potential applications in environmental and biomedical fields as well. The 3D macroporous MXene films are free‐standing, flexible, and highly conductive due to good contacts between spheres and metallic conductivity of MXenes. When used as anodes for sodium‐ion storage, these 3D MXene films exhibit much improved performances compared to multilayer MXenes and MXene/carbon nanotube hybrid architectures in terms of capacity, rate capability, and cycling stability. This work demonstrates the importance of MXene electrode architecture on the electrochemical performance and can guide future work on designing high‐performance MXene‐based materials for energy storage, catalysis, environmental, and biomedical applications.
Hollow Ti3C2Tx spheres and 3D macroporous MXene films are fabricated using a sacrificial template approach. The 3D MXene films are free‐standing, flexible, and highly conductive. They can serve directly as electrodes for Na‐ion storage and exhibit high capacities accompanied with excellent stabilities and rate performance.