Activation of supported nickel catalysts for carbon dioxide reforming of methane

• Published in: Applied catalysis. A, General Vol. 272; no. 1; pp. 133 - 139
• Main Authors: Souza, Mariana de M.V.M, Clavé, Lionel, Dubois, Vincent, Perez, Carlos A.C, Schmal, Martin
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 28-09-2004; Elsevier
• Subjects: Catalysis; Catalysts; Chemistry; Exact sciences and technology; General and physical chemistry; Methane; Nickel; Reforming; Syngas; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Methane; Reforming; Nickel; Catalysts; Syngas; Heterogeneous catalysis; Carbon dioxide; Transition metal; Activation; Synthesis gas; Supported catalyst; Catalyst support
• ISSN: 0926-860X; 1873-3875
• DOI: 10.1016/j.apcata.2004.05.026

A new activation process was proposed for supported nickel catalysts in CO
2 reforming of methane. The activation was performed by heating the catalyst up to 800
°C under a mixture of CH
4/O
2 = 2. Before activation the nickel catalysts present only nickel aluminate species; these species are partially reduced to metallic nickel during activation. SEM pictures showed formation of carbon filaments embedded with dispersed nickel particles, which are the active sites for methane reforming with CO
2. The nickel loading and the support greatly influence the catalyst stability, the conversion increased with Ni loading on alumina support, while the promotion with zirconia did not improve the catalytic behavior.