A Topotactic Synthetic Methodology for Highly Fluorine-Doped Mesoporous Metal Oxides
F tactic: Highly fluorine‐doped mesoporous metal oxides (up to 40 atom %) were synthesized by topotactic fluorination synthesis with mesoporous metal oxides as starting materials and fluorine as the fluorination agent. The surface areas, pore sizes, pore volumes, and F atomic concentrations of these...
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Published in: | Angewandte Chemie (International ed.) Vol. 51; no. 12; pp. 2888 - 2893 |
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Main Authors: | , , , , , , , |
Format: | Journal Article |
Language: | English |
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Weinheim
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19-03-2012
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Abstract | F tactic: Highly fluorine‐doped mesoporous metal oxides (up to 40 atom %) were synthesized by topotactic fluorination synthesis with mesoporous metal oxides as starting materials and fluorine as the fluorination agent. The surface areas, pore sizes, pore volumes, and F atomic concentrations of these materials could be adjusted over a wide range by varying the fluorination time and temperature. |
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AbstractList | F tactic: Highly fluorine‐doped mesoporous metal oxides (up to 40 atom %) were synthesized by topotactic fluorination synthesis with mesoporous metal oxides as starting materials and fluorine as the fluorination agent. The surface areas, pore sizes, pore volumes, and F atomic concentrations of these materials could be adjusted over a wide range by varying the fluorination time and temperature. |
Author | Dai, Sheng Adcock, Jamie Payzant, E. Andrew Veith, Gabriel M. Bauer, J. Chris Qiao, Zhen-an Unocic, Raymond R. Brown, Suree S. |
Author_xml | – sequence: 1 givenname: Zhen-an surname: Qiao fullname: Qiao, Zhen-an organization: Department of Chemistry, University of Tennessee, Knoxville, TN 37996 (USA) – sequence: 2 givenname: Suree S. surname: Brown fullname: Brown, Suree S. organization: Department of Chemistry, University of Tennessee, Knoxville, TN 37996 (USA) – sequence: 3 givenname: Jamie surname: Adcock fullname: Adcock, Jamie organization: Department of Chemistry, University of Tennessee, Knoxville, TN 37996 (USA) – sequence: 4 givenname: Gabriel M. surname: Veith fullname: Veith, Gabriel M. organization: Materials Science and Technology Division, Oak Ridge National Laboratory (USA) – sequence: 5 givenname: J. Chris surname: Bauer fullname: Bauer, J. Chris organization: Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (USA) – sequence: 6 givenname: E. Andrew surname: Payzant fullname: Payzant, E. Andrew organization: Center for Nanophase Material Sciences, Oak Ridge National Laboratory (USA) – sequence: 7 givenname: Raymond R. surname: Unocic fullname: Unocic, Raymond R. organization: Materials Science and Technology Division, Oak Ridge National Laboratory (USA) – sequence: 8 givenname: Sheng surname: Dai fullname: Dai, Sheng email: dais@ornl.gov organization: Department of Chemistry, University of Tennessee, Knoxville, TN 37996 (USA) |
BackLink | https://www.ncbi.nlm.nih.gov/pubmed/22311660$$D View this record in MEDLINE/PubMed https://www.osti.gov/biblio/1059328$$D View this record in Osti.gov |
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Notes | ArticleID:ANIE201107812 Office of Basic Energy Sciences, US Department of Energy ark:/67375/WNG-546N48JX-Z This work was sponsored by the Materials Sciences and Engineering Division (Z.A.Q., J.A., G.M.V., R.R.U., S.D.) and the Division of Chemical Sciences, Geosciences, and Biosciences (S.B., J.C.B.), Office of Basic Energy Sciences, US Department of Energy. A portion of this research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Office of Basic Energy Sciences, US Department of Energy. Microscopy was supported by ORNL's Shared Research Equipment (SHaRE) User Facility, which is sponsored by the Office of Basic Energy Sciences, US Department of Energy. istex:BF0CC0C9D72F06B1C68E6C1CAD53795BC8B14A71 This work was sponsored by the Materials Sciences and Engineering Division (Z.A.Q., J.A., G.M.V., R.R.U., S.D.) and the Division of Chemical Sciences, Geosciences, and Biosciences (S.B., J.C.B.), Office of Basic Energy Sciences, US Department of Energy. A portion of this research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Office of Basic Energy Sciences, US Department of Energy. Microscopy was supported by ORNL’s Shared Research Equipment (SHaRE) User Facility, which is sponsored by the Office of Basic Energy Sciences, US Department of Energy. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 DE-AC05-00OR22725 USDOE Office of Science (SC) |
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SubjectTerms | doping fluorine mesoporous materials synthetic methods |
Title | A Topotactic Synthetic Methodology for Highly Fluorine-Doped Mesoporous Metal Oxides |
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