A Topotactic Synthetic Methodology for Highly Fluorine-Doped Mesoporous Metal Oxides

F tactic: Highly fluorine‐doped mesoporous metal oxides (up to 40 atom %) were synthesized by topotactic fluorination synthesis with mesoporous metal oxides as starting materials and fluorine as the fluorination agent. The surface areas, pore sizes, pore volumes, and F atomic concentrations of these...

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Bibliographic Details
Published in:	Angewandte Chemie (International ed.) Vol. 51; no. 12; pp. 2888 - 2893
Main Authors:	Qiao, Zhen-an, Brown, Suree S., Adcock, Jamie, Veith, Gabriel M., Bauer, J. Chris, Payzant, E. Andrew, Unocic, Raymond R., Dai, Sheng
Format:	Journal Article
Language:	English
Published:	Weinheim WILEY-VCH Verlag 19-03-2012 WILEY‐VCH Verlag Wiley Subscription Services, Inc
Edition:	International ed. in English
Subjects:	doping fluorine mesoporous materials synthetic methods
Online Access:	Get full text
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Summary:	F tactic: Highly fluorine‐doped mesoporous metal oxides (up to 40 atom %) were synthesized by topotactic fluorination synthesis with mesoporous metal oxides as starting materials and fluorine as the fluorination agent. The surface areas, pore sizes, pore volumes, and F atomic concentrations of these materials could be adjusted over a wide range by varying the fluorination time and temperature.
Bibliography:	ArticleID:ANIE201107812 Office of Basic Energy Sciences, US Department of Energy ark:/67375/WNG-546N48JX-Z This work was sponsored by the Materials Sciences and Engineering Division (Z.A.Q., J.A., G.M.V., R.R.U., S.D.) and the Division of Chemical Sciences, Geosciences, and Biosciences (S.B., J.C.B.), Office of Basic Energy Sciences, US Department of Energy. A portion of this research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Office of Basic Energy Sciences, US Department of Energy. Microscopy was supported by ORNL's Shared Research Equipment (SHaRE) User Facility, which is sponsored by the Office of Basic Energy Sciences, US Department of Energy. istex:BF0CC0C9D72F06B1C68E6C1CAD53795BC8B14A71 This work was sponsored by the Materials Sciences and Engineering Division (Z.A.Q., J.A., G.M.V., R.R.U., S.D.) and the Division of Chemical Sciences, Geosciences, and Biosciences (S.B., J.C.B.), Office of Basic Energy Sciences, US Department of Energy. A portion of this research was conducted at the Center for Nanophase Materials Sciences, which is sponsored at Oak Ridge National Laboratory by the Office of Basic Energy Sciences, US Department of Energy. Microscopy was supported by ORNL’s Shared Research Equipment (SHaRE) User Facility, which is sponsored by the Office of Basic Energy Sciences, US Department of Energy. ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23 DE-AC05-00OR22725 USDOE Office of Science (SC)
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.201107812