A review of the identification and detection of heavy metal ions in the environment by voltammetry

• Published in: Talanta (Oxford) Vol. 178; pp. 324 - 338
• Main Authors: Lu, Yuanyuan, Liang, Xinqiang, Niyungeko, Christophe, Zhou, Junjie, Xu, Jianming, Tian, Guangming
• Format: Journal Article
• Language: English
• Published: Netherlands Elsevier B.V 01-02-2018
• Subjects: Heavy metal ions; Modified electrode; Nanomaterials; Sensors; Voltammetry; CTS; Modified electrode; CNFs; LSSV; FAAS; ZnO NFs; Sensors; ICP-OES; BiFEs; ICP-AES; PBS; Heavy metal ions; SWCNTs; AG; CMEs; Nanomaterials; HMIs; LSV; EIS; SAMs; AAS; RE; SWASV; MWCNTs; ICP-MS; RGO; DPASV; ZnO NTs; Voltammetry; DPV; SPEs; WE; DPSV; CNTs; SWSV; CE; SPCEs; ASV; NCEs; GCE; GO; VACNF; NEA; EDTA; NPs; CV; SWV; BRB; ERGO; CPE
• ISSN: 0039-9140; 1873-3573
• DOI: 10.1016/j.talanta.2017.08.033

Currently, environmental pollution by heavy metals is a global problem. Therefore, it is crucial to develop effective detection techniques to determine the levels of heavy metal contamination in various mediums. Voltammetry is a highly sensitive electrochemical method used for the in situ detection of heavy metal ions. This study investigates the current trends related to electrode modification, developments in materials, and optimization of the experimental parameters. We discuss the sensing performance of four kinds of nanomaterials capable of inorganic modification (metal nanoparticles, metal oxides, carbonaceous nanomaterials, and their nanocomposites). The impact of several important factors, such as the deposition potential and time, buffer solution types, and pH on the sensitivity, reproducibility, stability, and anti-interference ability of the detection process, especially with regard to the co-detection of several heavy metal ions, was reviewed. We noted that in addition to the application of voltammetry to water-related issues, it is suitable for rapid and simple identification and analyses of heavy metals in polluted soil and other mediums. Thus, it is important to conduct additional research on the application of voltammetry to this area.
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•Basic principles of voltammetry for heavy metal detection were reviewed.•The sensing performance of inorganic nanomaterials modification were discussed.•The impact of several important experimental factors were emphasized.•The application of voltammetry involves in many mediums.