Sag in drying coatings: Prediction and real time measurement with particle tracking

• Published in: Progress in organic coatings Vol. 86; pp. 49 - 58
• Main Authors: Lade, Robert K., Song, Jin-Oh, Musliner, Austin D., Williams, Bryce A., Kumar, Satish, Macosko, Christopher W., Francis, Lorraine F.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 01-09-2015
• Subjects: Coatings; Drying; Lycopodium; Mathematical models; Paints; Particle tracking; Polyvinyl alcohols; Protective coatings; Real time; Regime map; Rheology; Sag; Sag; Regime map; Rheology; Particle tracking; Lycopodium; Drying
• ISSN: 0300-9440; 1873-331X
• DOI: 10.1016/j.porgcoat.2015.04.005

•A novel method for monitoring sag in drying coatings is developed.•Lycopodium spores are used to track surface velocity using optical microscopy.•Experimentally measured velocities agree well with those predicted using a model.•A sag regime map, which predicts sag extent from coating properties, is presented.
Sag is a coating phenomenon characterized by gravity-driven flow after deposition; excessive amounts of sag can lead to coating defects. In this work, a new method for evaluating and quantifying sag is investigated. The motion of micron-sized Lycopodium spores on an inclined coating surface is tracked during drying, and the resulting surface velocity data is used to determine sag length. This in situ particle tracking method is minimally invasive and permits real time measurements. Measured sag lengths and real time surface velocities in aqueous polyvinyl alcohol solution coatings compare well with a theoretical model. The model is also used to develop a predictive sag regime map, which anticipates the extent of sag given coating properties and process-specific parameters. This map also identifies viable processing windows and aids in intelligent coating design given specific process constraints. The predictions of the sag regime map are compared against experimental sag results from polyvinyl alcohol solution coatings as well as four commercial latex paints, revealing good agreement for coatings with Newtonian or ‘Newtonian-like’ rheologies.