Glow discharge nitriding in AISI 304 at different nitrogen–hydrogen atmospheres: Structural, mechanical and tribological properties

• Published in: Materials science & engineering. A, Structural materials : properties, microstructure and processing Vol. 489; no. 1; pp. 201 - 206
• Main Authors: Lepienski, C.M., Nascimento, F.C., Foerster, C.E., da Silva, S.L.R., de M. Siqueira, C.J., Alves, C.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 20-08-2008; Elsevier
• Subjects: Applied sciences; Contact of materials. Friction. Wear; Exact sciences and technology; Glow discharge; Heat treatment; Instrumented indentation; Mechanical properties; Mechanical properties and methods of testing. Rheology. Fracture mechanics. Tribology; Metals. Metallurgy; Nitriding; Production techniques; Rietveld refinement; Thermochemical treatment and diffusion treatment; Tribology; 62.20.Qp; Instrumented indentation; Rietveld refinement; 81.05.Bx; Glow discharge; Mechanical properties; Nitriding; 81.40.Pq; 81.40.Wx; 81.65.Lp; Tribology; Phase composition; Surface hardening; Sliding wear; Hardness; Controlled atmosphere; Indentation; Stainless steel-304; Microstructure
• ISSN: 0921-5093; 1873-4936
• DOI: 10.1016/j.msea.2007.12.012

Structural, mechanical and tribological properties of AISI 304 steel submitted to nitrogen glow discharge at different atmospheres (N
2:H
2, 60:40) and (N
2:H
2, 20:80) and substrate temperatures are reported. Expanded austenite γ
N and Fe–Cr nitrides were identified as a function of the working conditions. Rietveld refinements indicate that ɛ-Fe
2+
x
N is the predominant phase for the poorest nitrogen atmosphere while γ′-Fe
4N phase is major for the richest one. The nitriding produces a surface hardening that can reach hardness values up to 14
GPa. Thicker nitrided regions are obtained in high nitriding temperatures. Reciprocating sliding tests in samples with rich or poor nitrogen atmosphere indicated long running-in regimes for high nitriding temperature. Both nitrogen atmospheres reduced the wear up to a factor of six even at the lowest temperature process. The nanoscratch tests do not show difference in the surface elastic recovering in all used nitriding conditions.