Atmospheric nitrous acid (HONO) at a rural coastal site in North China: Seasonal variations and effects of biomass burning

• Published in: Atmospheric environment (1994) Vol. 229; p. 117429
• Main Authors: Gu, Rongrong, Zheng, Penggang, Chen, Tianshu, Dong, Can, Wang, Ya'nan, Liu, Yiming, Liu, Yuhong, Luo, Yuanyuan, Han, Guangxuan, Wang, Xinfeng, Zhou, Xuehua, Wang, Tao, Wang, Wenxing, Xue, Likun
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 15-05-2020
• Subjects: Biomass burning; Hydroxyl radical; Nitrous acid; North China; Seasonal variation; North China; Seasonal variation; Biomass burning; Nitrous acid; Hydroxyl radical
• ISSN: 1352-2310; 1873-2844
• DOI: 10.1016/j.atmosenv.2020.117429

Nitrous acid (HONO) plays a significant role in atmospheric chemistry due to its contribution to hydroxyl radical (OH). However, no scientific consensus has been achieved about the daytime HONO formation mechanisms. To identify the seasonal variations of HONO chemistry and the impacts of biomass burning (BB), we performed a two-phased field study in winter-spring and summer (covering a harvest season) in 2017 at a rural coastal site in North China. Though the mean HONO concentration in winter-spring (0.26 ± 0.28 ppbv) was higher than in summer (0.17 ± 0.19 ppbv), the maximum HONO concentrations were comparable (~2 ppbv) in the two campaigns. Both the HONO/NOx ratio and nocturnal heterogeneous conversion efficiency of HONO (CHONO) in summer were over twice of that in winter-spring. The daytime budget analysis also revealed that the strength of Pother (i.e., the HONO sources apart from the reaction of OH + NO) in summer was double of that in winter-spring. BB affected the HONO concentration by enhancing the contribution of heterogeneous HONO production on the aerosol surface but weakening the role of photo-related HONO formation. HONO photolysis was a significant source of OH in both winter-spring and summer, and its contribution could be further enhanced during the BB episode in summer. Our study demonstrates the significant seasonal variations of HONO and the effects of BB, and suggests needs for more multi-season observations and considerations of BB, especially during the harvest time, in HONO research.
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•Significant seasonal variations of HONO pollution and chemistry were found.•Source strength of HONO can be enhanced by solar radiation and biomass burning.•Biomass burning enhanced the role of aerosol in heterogeneous HONO formation.