Insulator-Conductor Type Transitions in Graphene-Modified Silver Nanowire Networks: A Route to Inexpensive Transparent Conductors

• Published in: Advanced functional materials Vol. 24; no. 48; pp. 7580 - 7587
• Main Authors: Jurewicz, Izabela, Fahimi, Azin, Lyons, Phillip E., Smith, Ronan J., Cann, Maria, Large, Matthew L., Tian, Mingwen, Coleman, Jonathan N., Dalton, Alan B.
• Format: Journal Article
• Language: English
• Published: Blackwell Publishing Ltd 23-12-2014
• Subjects: Coatings; Conduction; Electrodes; Graphene; hybrid materials; langmuir schaefer; Nanowires; Networks; pristine graphene; Silver; silver nanowires; Touch screens
• ISSN: 1616-301X; 1616-3028
• DOI: 10.1002/adfm.201402547

Silver nanowire coatings are an attractive alternative to indium tin oxide for producing transparent conductors. To fabricate coatings with low sheet resistance required for touchscreen displays, a multi‐layer network of silver nanowires must be produced that may not be cost effective. This problem is counteracted here by modifying the electrical properties of an ultra‐low‐density nanowire network through local deposition of conducting graphene platelets. Unlike other solution‐processed materials, such as graphene oxide, our pristine graphene is free of oxygen functional groups, resulting in it being electrically conducting without the need for further chemical treatment. Graphene adsorption at inter‐wire junctions as well as graphene connecting adjacent wires contributes to a marked enhancement in electrical properties. Using our approach, the amount of nanowires needed to produce viable transparent electrodes could be more than 50 times less than the equivalent pristine high density nanowire networks, thus having major commercial implications. Using a laser ablation process, it is shown that the resulting films can be patterned into individual electrode structures, which is a pre‐requisite to touchscreen sensor fabrication.
A simple, scalable, and relatively inexpensive method is described for preparing highly conducting AgNW/graphene hybrid transparent electrodes that use low‐cost solution‐processed pristine graphene. A combination of spray deposition and Langmuir‐based techniques is used to produce ultrathin films with controlled nanowire and graphene densities. The results indicate that these graphene/nanowire hybrid films may serve as a cheap replacement for existing technologies in electronic devices.