Computer simulation of granule microstructure formation

• Published in: Chemical engineering science Vol. 60; no. 14; pp. 4019 - 4029
• Main Authors: Štěpánek, F., Ansari, M.A.
• Format: Journal Article
• Language: English
• Published: Oxford Elsevier Ltd 01-07-2005; Elsevier
• Subjects: Agglomeration; Applied sciences; Chemical engineering; Diagenesis; Exact sciences and technology; Microstructure; Porosity; Product design; Sintering, pelletization, granulation; Solid-solid systems; Wetting; Diagenesis; Agglomeration; Product design; Porosity; Wetting; Microstructure; Cartography; Particle size; Granulation; Computer simulation; Droplet; Binders; Particle collision; Modeling; Operating conditions; Solidification; Spreading; Morphology; Growth mechanism; Numerical simulation; Product development; Granule
• ISSN: 0009-2509; 1873-4405
• DOI: 10.1016/j.ces.2005.02.030

The diagenesis (porous microstructure evolution) of granules formed by a layering growth mechanism in a wet granulation process has been modelled. The model includes the packing of primary particles with a given size and shape distribution, and the deposition, spreading, and solidification of binder droplets within the growing granule. The dependence of granule porosity on the binder/solids ratio, primary particle size and morphology, and the rates of binder spreading and solidification has been investigated. The results are presented in the form of structure maps relating volume-averaged microstructure parameters with dimensionless groups including the ratio of droplet spreading and solidification times and the mean time between particle collisions. These graphs can guide the selection of process operating conditions or formulation ingredient properties required to obtain a particular granule microstructure.