Palladium-Catalyzed Cross-Coupling Reaction Using Arylgermanium Sesquioxide

Palladium-Catalyzed Cross-Coupling Reaction Using Arylgermanium Sesquioxide

Powdery reagents obtained by complete alkaline hydrolysis of arylgermanium trichlorides were found to undergo the palladium‐catalyzed cross‐coupling reaction with aryl bromides and iodides in good yields. The reaction is performed in an aqueous medium taking sodium hydroxide as an activator. Some ba...

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Bibliographic Details
Published in:Advanced synthesis & catalysis Vol. 349; no. 7; pp. 1025 - 1027
Main Authors: Endo, Mayuko, Fugami, Keigo, Enokido, Tatsuki, Sano, Hiroshi, Kosugi, Masanori
Format: Journal Article
Language:English
Published: Weinheim WILEY-VCH Verlag 07-05-2007
WILEY‐VCH Verlag
Subjects:
biaryls
cross-coupling
germanium
palladium
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Description
Summary:Powdery reagents obtained by complete alkaline hydrolysis of arylgermanium trichlorides were found to undergo the palladium‐catalyzed cross‐coupling reaction with aryl bromides and iodides in good yields. The reaction is performed in an aqueous medium taking sodium hydroxide as an activator. Some base‐sensitive functionalities such as acetyl and trifluoromethyl groups survived the reaction.
Bibliography:istex:1A6CE712CF269D3AB1301DC9CE76C4322B3CB8EC
ark:/67375/WNG-LMHVQGLG-P
ArticleID:ADSC200700002
ObjectType-Article-2
SourceType-Scholarly Journals-1
ObjectType-Feature-1
content type line 23
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.200700002