Determining processing behaviour of pure Cu in laser powder bed fusion using direct micro-calorimetry

• Published in: Journal of materials processing technology Vol. 294; no. C; p. 117130
• Main Authors: Gargalis, Leonidas, Ye, Jianchao, Strantza, Maria, Rubenchik, Alexander, Murray, James W., Clare, Adam T., Ashcroft, Ian A., Hague, Richard, Matthews, Manyalibo J.
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01-08-2021; Elsevier BV; Elsevier
• Subjects: Absorptivity; Additive manufacturing; Copper; Direct micro-calorimetry; Heat conductivity; Heat measurement; Heat transfer; Infrared laser diode; Infrared lasers; Laser beam heating; Laser powder bed fusion; Lasers; Melting; Optimization; Powder beds; Process parameters; Semiconductor lasers; Thermal conductivity; Thickness; Infrared laser diode; Laser powder bed fusion; Absorptivity; Additive manufacturing; Copper; Direct micro-calorimetry
• ISSN: 0924-0136; 1873-4774
• DOI: 10.1016/j.jmatprotec.2021.117130

Copper is challenging to process by laser powder bed fusion (LPBF) given its high reflectivity at common infrared laser diode wavelengths and high thermal conductivity. Successful deposition of copper in a predictable and repeatable fashion relies on understanding the development of the keyhole melting regime, as well as heating, melting, boiling and vapour formation behaviour when interacting with a laser beam within an LPBF environment. In this study, in situ optical absorptivity measurements are used to clarify the complex physics of the laser material interaction. Absorptivity of laser energy is measured using direct micro-calorimetry and compared to melt pool depth in correlation to processing parameters. The measured absorptivity for a 100 μm layer thickness of powder was found to be approximately four times higher than that of the bare polished discs. It was also shown that high laser power above 500 W and scan speed up to 150 mm/s are appropriate for effective melting of the powder layer, with these parameters overcoming the threshold required to achieve keyhole melting. This is explained by multiple reflections withing the powder particles and the lower thermal conductivity of packed powder in comparison to bare discs. Melt pool formation was found to be highly unstable and an explosive behavior was observed when in the keyhole regime, caused by high fluctuations in absorptivity values. This work demonstrates calorimetry can be used to monitor melting behaviour in a real-time fashion during processing for this challenging to proces material, thereby avoiding unnecessary parametric optimisation. In addition, the parametric window for optimum processing revealed here can inform future work.