First Report on Thermally Stable Cadmium Carbonyl Complex Containing an Interesting Chloroaryl Bridge: Isolation and Characterization

First Report on Thermally Stable Cadmium Carbonyl Complex Containing an Interesting Chloroaryl Bridge: Isolation and Characterization

A novel thermally stable tetranuclear cadmium carbonyl complex [Cd(CO)3(C6H3Cl)]4·2H2O has been synthesized for the first time through a green path with an overall yield of 35%. The synthetic route features a new pathway, creating the two ortho-positions with respect to the chlorine atom in the aryl...

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Bibliographic Details
Published in:Chemistry letters Vol. 40; no. 8; pp. 810 - 812
Main Authors: Dey, Subrata K, Shit, Shyamapada, Dey, Sankar P, Mitra, Samiran, Malik, K. M. Abdul
Format: Journal Article
Language:English
Published: The Chemical Society of Japan 05-08-2011
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Summary:A novel thermally stable tetranuclear cadmium carbonyl complex [Cd(CO)3(C6H3Cl)]4·2H2O has been synthesized for the first time through a green path with an overall yield of 35%. The synthetic route features a new pathway, creating the two ortho-positions with respect to the chlorine atom in the aryl rings for bridging two cadmium metal centers. The title complex has been characterized by microanalytical, infrared spectroscopic, and thermal methods while its structure has been established by single-crystal X-ray diffraction supported by 1H, 13C, and 113Cd NMR data.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2011.810