Effect of soil amendments on the sorption behavior of atrazine in sandy loam soil

• Published in: Environmental monitoring and assessment Vol. 195; no. 6; p. 686
• Main Authors: Khan, Saif Ullah, Kumar, Anup, Prasad, Mahendra, Upadhyay, Deepak, Mehta, Brijesh K., Shashikumara, P, Tamboli, Pooja
• Format: Journal Article
• Language: English
• Published: Cham Springer International Publishing 01-06-2023; Springer Nature B.V
• Subjects: Adsorption; Animal manures; Atmospheric Protection/Air Quality Control/Air Pollution; Atrazine; Atrazine - analysis; Composting; Crops; Earth and Environmental Science; Ecology; Ecosystem; Ecotoxicology; Environment; Environmental Management; Environmental Monitoring; Environmental science; Farms; Free energy; Herbicides; Herbicides - analysis; Kinetics; Loam; Loam soils; Mixtures; Monitoring/Environmental Analysis; Pesticides; Sand; Sandy loam; Sandy soils; Soil; Soil adsorption; Soil amendment; Soil mixtures; Soil Pollutants - analysis; Soils; Sorption; Toxicity; Tropical environment; Tropical environments; Vermicomposting; Worms; Desorption; Models; Adsorption; Triazine herbicide; Amendments
• ISSN: 0167-6369; 1573-2959
• DOI: 10.1007/s10661-023-11292-9

The sorption behavior of pesticides applied during cultivation of crops is affected by amendments such as farm yard manure (FYM) and vermicompost (VC) during land preparation. Among pesticides, atrazine, a widely used herbicide in many crops, was analyzed for its kinetics and sorption behavior through the addition of FYM and VC in sandy loam soil. The pseudo-second-order (PSO) model best fit the kinetics results in the recommended dose of FYM and VC mixed soil. More atrazine was sorbed onto VC mixed soil than FYM mixed soil. In comparison to control (no amendment), both FYM and VC (1, 1.5, and 2%) increased atrazine adsorption, but the effect varied with dosage and type of amendment. The Freundlich adsorption isotherm adequately explained atrazine adsorption in soil/soil + (FYM/VC) mixtures, and the adsorption was highly nonlinear. The values of Gibb’s free energy change (Δ
G
) were negative for both adsorption and desorption in soil/soil + (FYM/VC) mixtures, suggesting sorption was exothermic and spontaneous in nature. The results revealed that the application of amendments used by farmers interferes the availability, mobility, and infiltration of atrazine in the soil. Therefore, the findings of this study suggest that amendments such as FYM and VC can be effectively used to minimize the residual toxicity of atrazine-treated ago-ecosystems in tropical and sub-tropical regions.