Degradation of graphene coated copper in simulated proton exchange membrane fuel cell environment: Electrochemical impedance spectroscopy study

• Published in: Journal of power sources Vol. 362; pp. 366 - 372
• Main Authors: Ren, Y.J., Anisur, M.R., Qiu, W., He, J.J., Al-Saadi, S., Singh Raman, R.K.
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15-09-2017
• Subjects: Bipolar plates; Corrosion; Electrochemical impedance spectroscopy (EIS); Graphene coatings; Proton exchange membrane fuel cell (PEMFC); Proton exchange membrane fuel cell (PEMFC); Corrosion; Electrochemical impedance spectroscopy (EIS); Bipolar plates; Graphene coatings
• ISSN: 0378-7753; 1873-2755
• DOI: 10.1016/j.jpowsour.2017.07.041

Metallic materials are most suitable for bipolar plates of proton exchange membrane fuel cell (PEMFC) because they possess the required mechanical strength, durability, gas impermeability, acceptable cost and are suitable for mass production. However, metallic bipolar plates are prone to corrosion or they can passivate under PEMFC environment and interrupt the fuel cell operation. Therefore, it is highly attractive to develop corrosion resistance coating that is also highly conductive. Graphene fits these criteria. Graphene coating is developed on copper by chemical vapor deposition (CVD) with an aim to improving corrosion resistance of copper under PEMFC condition. The Raman Spectroscopy shows the graphene coating to be multilayered. The electrochemical degradation of graphene coated copper is investigated by electrochemical impedance spectroscopy (EIS) in 0.5 M H2SO4 solution at room temperature. After exposure to the electrolyte for up to 720 h, the charge transfer resistance (Rt) of the graphene coated copper is ∼3 times greater than that of the bare copper, indicating graphene coatings could improve the corrosion resistance of copper bipolar plates.
•Graphene coatings are deposited on copper bipolar plates of PEMFC by CVD.•The degradation of graphene coated copper in sulfuric acid is investigated by EIS.•The charge transfer resistance of graphene coating is ∼3 times greater than copper.•The excellent conductivity of graphene enhances its corrosion resistance.