3-Iodo-3-trimethylsilylpropenal as a Useful Unit for Pinacol Coupling and Subsequent Functional Group Transformations

3-Iodo-3-trimethylsilylpropenal as a Useful Unit for Pinacol Coupling and Subsequent Functional Group Transformations

Titanium tetraiodidesilyl-mediated pinacol coupling reaction of (Z)-3-iodo-3-trimethylsilylpropenal is used for the preparation of trans-4,5-bis[(Z)-2-iodo-2-(trimethylsilyl)vinyl]-2,2-dimethyl-1,3-dioxolane, which is utilized for the subsequent C–C bond-forming reactions.

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Bibliographic Details
Published in:Chemistry letters Vol. 37; no. 1; pp. 28 - 29
Main Authors: Shimizu, Makoto, Okimura, Hisashi, Manabe, Nobuyuki, Hachiya, Iwao
Format: Journal Article
Language:English
Published: Tokyo The Chemical Society of Japan 05-01-2008
Chemical Society of Japan
Online Access:Get full text
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Description
Summary:Titanium tetraiodidesilyl-mediated pinacol coupling reaction of (Z)-3-iodo-3-trimethylsilylpropenal is used for the preparation of trans-4,5-bis[(Z)-2-iodo-2-(trimethylsilyl)vinyl]-2,2-dimethyl-1,3-dioxolane, which is utilized for the subsequent C–C bond-forming reactions.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2008.28