π‐Interpenetrated 3D Covalent Organic Frameworks from Distorted Polycyclic Aromatic Hydrocarbons

Three‐dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic (D3d) nodes. Such 3D COFs are six‐fold interpenetrated as the result of interframework π‐stacking, which enable charge tra...

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Bibliographic Details
Published in:	Angewandte Chemie International Edition Vol. 60; no. 18; pp. 9941 - 9946
Main Authors:	Martínez‐Abadía, Marta, Strutyński, Karol, Lerma‐Berlanga, Belén, Stoppiello, Craig T., Khlobystov, Andrei N., Martí‐Gastaldo, Carlos, Saeki, Akinori, Melle‐Franco, Manuel, Mateo‐Alonso, Aurelio
Format:	Journal Article
Language:	English
Published:	Germany Wiley Subscription Services, Inc 26-04-2021
Edition:	International ed. in English
Subjects:	3D covalent organic frameworks Charge transport interpenetration non-planar aromatics Polycyclic aromatic hydrocarbons Topology Transport properties interpenetration non-planar aromatics 3D covalent organic frameworks polycyclic aromatic hydrocarbons charge transport
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Summary:	Three‐dimensional covalent organic frameworks (3D COFs) with a pcu topology have been obtained from distorted polycyclic aromatic hydrocarbons acting as triangular antiprismatic (D3d) nodes. Such 3D COFs are six‐fold interpenetrated as the result of interframework π‐stacking, which enable charge transport properties that are not expected for 3D COFs. Three‐dimensional covalent organic frameworks (3D COFs) have been obtained from distorted polycyclic aromatic hydrocarbon nodes. Interframework π‐stacking enables charge transport properties that are not expected for 3D COFs.
Bibliography:	ObjectType-Article-1 SourceType-Scholarly Journals-1 ObjectType-Feature-2 content type line 23
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.202100434