A novel route for catalytic activation of peroxymonosulfate by oxygen vacancies improved bismuth-doped titania for the removal of recalcitrant organic contaminant

• Published in: Environmental science and pollution research international Vol. 28; no. 18; pp. 23368 - 23385
• Main Authors: Gul, Ikhtiar, Sayed, Murtaza, Shah, Noor S., Rehman, Faiza, Khan, Javed Ali, Gul, Saman, Bibi, Noorina, Iqbal, Jibran
• Format: Journal Article
• Language: English
• Published: Berlin/Heidelberg Springer Berlin Heidelberg 01-05-2021; Springer Nature B.V
• Subjects: Acids; Anatase; Aquatic environment; Aquatic Pollution; Atmospheric Protection/Air Quality Control/Air Pollution; Biodegradation; Bismuth; Bonding strength; Catalysts; Chemistry; Cobalt; Contaminants; Crystal lattices; Degradation; Dominant species; Earth and Environmental Science; Ecotoxicology; Environment; Environmental Chemistry; Environmental cleanup; Environmental Health; Environmental science; Flumequine; Ionization; Lattice vacancies; Leaching; Microorganisms; Mineralization; Organic contaminants; Oxidation; Oxidation process; Oxygen; Photocatalysis; Porosity; Research Article; Scavenging; Sol-gel processes; Strong interactions (field theory); Titanium; Titanium dioxide; Waste Water Technology; Water Management; Water Pollution Control; Flumequine; Water treatment; Bismuth-doped titania; activation under dark; HSO; Oxygen vacancy; HSO5 − activation under dark
• ISSN: 0944-1344; 1614-7499
• DOI: 10.1007/s11356-020-11497-2

In this work, bismuth-doped titania (Bi
x
TiO
2
) with improved oxygen vacancies was synthesized by sol-gel protocol as a novel peroxymonosulfate (PMS, HSO
5
−
) activator. HSO
5
−
and adsorbed oxygen molecules could efficiently be transformed into their respective radicals through defect ionization to attain charge balance after their trapping on oxygen vacancies of the catalyst. XRD study of Bi
x
TiO
2
with 5 wt% Bi (5BiT) revealed anatase, crystalline nature, and successful doping of Bi into TiO
2
crystal lattice. The particle size obtained from BET data and SEM observations was in good agreement. PL spectra showed the formation rates of
•
OH by 3BiT, 7BiT, 5BiTC, and 5BiT as 0.720, 1.200, 1.489, and 2.153 μmol/h, respectively. 5BiT catalyst with high surface area (216.87 m
2
g
−1
) and high porosity (29.81%) was observed the excellent HSO
5
−
activator. The catalytic performance of 0BiT, 3BiT, 5BiT, and 7BiT when coupled with 2 mM HSO
5
−
for recalcitrant flumequine (FLU) removal under dark was 10, 27, 55, and 37%, respectively. Only 5.4% decrease in catalytic efficiency was observed at the end of seventh cyclic run. Radical scavenging studies indicate that SO
4
•−
is the dominant species that caused 62.0% degradation. Moreover, strong interaction between Bi and TiO
2
through Bi-O-Ti bonds prevents Bi leaching (0.081 mg L
−1
) as shown by AAS. The kinetics, degradation pathways, ecotoxicity, and catalytic mechanism for recalcitrant FLU were also elucidated. Cost-efficient, environment-friendly, and high mineralization recommends this design strategy; Bi
x
TiO
2
/HSO
5
−
system is a promising advanced oxidation process for the aquatic environment remediation.