Flexible, High‐Wettability and Fire‐Resistant Separators Based on Hydroxyapatite Nanowires for Advanced Lithium‐Ion Batteries

• Published in: Advanced materials (Weinheim) Vol. 29; no. 44
• Main Authors: Li, Heng, Wu, Dabei, Wu, Jin, Dong, Li‐Ying, Zhu, Ying‐Jie, Hu, Xianluo
• Format: Journal Article
• Language: English
• Published: Germany Wiley Subscription Services, Inc 01-11-2017
• Subjects: Cellulose fibers; Contact angle; Crosslinking; Electrochemical analysis; Electrolytes; Fire resistance; fire resistant; Fire resistant materials; high safety; Hydroxyapatite; hydroxyapatite nanowires; Lithium; Lithium-ion batteries; Materials science; Nanowires; Product safety; Rechargeable batteries; Separators; Structural hierarchy; Structural integrity; Thermal resistance; Thermal stability; Wettability; hydroxyapatite nanowires; lithium-ion batteries; separators; high safety; fire resistant
• ISSN: 0935-9648; 1521-4095
• DOI: 10.1002/adma.201703548

Separators play a pivotal role in the electrochemical performance and safety of lithium‐ion batteries (LIBs). The commercial microporous polyolefin‐based separators often suffer from inferior electrolyte wettability, low thermal stability, and severe safety concerns. Herein, a novel kind of highly flexible and porous separator based on hydroxyapatite nanowires (HAP NWs) with excellent thermal stability, fire resistance, and superior electrolyte wettability is reported. A hierarchical cross‐linked network structure forms between HAP NWs and cellulose fibers (CFs) via hybridization, which endows the separator with high flexibility and robust mechanical strength. The high thermal stability of HAP NW networks enables the separator to preserve its structural integrity at temperatures as high as 700 °C, and the fire‐resistant property of HAP NWs ensures high safety of the battery. In particular, benefiting from its unique composition and highly porous structure, the as‐prepared HAP/CF separator exhibits near zero contact angle with the liquid electrolyte and high electrolyte uptake of 253%, indicating superior electrolyte wettability compared with the commercial polyolefin separator. The as‐prepared HAP/CF separator has unique advantages of superior electrolyte wettability, mechanical robustness, high thermal stability, and fire resistance, thus, is promising as a new kind of separator for advanced LIBs with enhanced performance and high safety.
A new kind of highly flexible, porous, high‐wettability, fire‐resistant hydroxyapatite nanowire‐based separator with superior performance and high safety is prepared for advanced lithium‐ion batteries. The batteries with the hydroxyapatite nanowire‐based separators show better cyclability and enhanced rate capability compared with those with the commercial polypropylene separator. The as‐prepared batteries adopting the hydroxyapatite nanowire‐based separator can safely work at 150 °C.