A review on chemiresistive room temperature gas sensors based on metal oxide nanostructures, graphene and 2D transition metal dichalcogenides

• Published in: Mikrochimica acta (1966) Vol. 185; no. 4; pp. 213 - 16
• Main Authors: Joshi, Nirav, Hayasaka, Takeshi, Liu, Yumeng, Liu, Huiliang, Oliveira, Osvaldo N., Lin, Liwei
• Format: Journal Article
• Language: English
• Published: Vienna Springer Vienna 01-04-2018; Springer; Springer Nature B.V
• Subjects: Acetone; Ammonia; Analytical Chemistry; Chalcogenides; Characterization and Evaluation of Materials; Chemistry; Chemistry and Materials Science; Detection; Gas sensors; Gases; Graphene; Graphite; Metal oxides; Microengineering; Nanochemistry; Nanostructure; Nanotechnology; Nickel; Nitrogen oxide; Nitrogen oxides; Noble metals; Review Article; Room temperature; Sensors; Transition metal compounds; Sensitivity; Surface reaction; Semiconductors; Nanosensors, 2D Materials; Selectivity; Chemiresistive gas sensors; Thin Films; Gas sensors
• ISSN: 0026-3672; 1436-5073
• DOI: 10.1007/s00604-018-2750-5

Room-temperature (RT) gas sensing is desirable for battery-powered or self-powered instrumentation that can monitor emissions associated with pollution and industrial processes. This review (with 171 references) discusses recent advances in three types of porous nanostructures that have shown remarkable potential for RT gas sensing. The first group comprises hierarchical oxide nanostructures (mainly oxides of Sn, Ni, Zn, W, In, La, Fe, Co). The second group comprises graphene and its derivatives (graphene, graphene oxides, reduced graphene oxides, and their composites with metal oxides and noble metals). The third group comprises 2D transition metal dichalcogenides (mainly sulfides of Mo, W, Sn, Ni, also in combination with metal oxides). They all have been found to enable RT sensing of gases such as NOx, NH
3
, H
2
, SO
2
, CO, and of vapors such as of acetone, formaldehyde or methanol. Attractive features also include high selectivity and sensitivity, long-term stability and affordable costs. Strengths and limitations of these materials are highlighted, and prospects with respect to the development of new materials to overcome existing limitations are discussed.
Graphical Abstract
The review summarizes the most significant progresses related to room temperature gas sensing by using hierarchical oxide nanostructures, graphene and its derivatives and 2D transition metal dichalcogenides, highlighting the peculiar gas sensing behavior with enhanced selectivity, sensitivity and long-term stability.