Lanthanide dithiocarbamate complexes: efficient catalysts for the cyanosilylation of aldehydes

A new class of lanthanide dithiocarbamate complexes was used to promote the cyanosilylation of aldehydes at high yields at room temperature. This represents the first application of lanthanide dithiocarbamate acting as Lewis acid.

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Bibliographic Details
Published in:	Journal of the Brazilian Chemical Society Vol. 17; no. 5; pp. 829 - 831
Main Authors:	Vale, Juliana A., Faustino, Wagner M., Menezes, Paulo H., Sá, Gilberto F. de
Format:	Journal Article
Language:	English
Published:	Sociedade Brasileira de Química 01-10-2006
Subjects:	CHEMISTRY, MULTIDISCIPLINARY Lewis acid cyanohydrins lanthanide dithiocarbamate cyanosilylation
Online Access:	Get full text
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Description
Summary:	A new class of lanthanide dithiocarbamate complexes was used to promote the cyanosilylation of aldehydes at high yields at room temperature. This represents the first application of lanthanide dithiocarbamate acting as Lewis acid.
ISSN:	0103-5053 1678-4790
DOI:	10.1590/S0103-50532006000500002