Green synthesis of Cu-doped ZnO nanoparticles and its application for the photocatalytic degradation of hazardous organic pollutants

• Published in: Chemosphere (Oxford) Vol. 287; p. 132081
• Main Authors: Karthik, K.V., Raghu, A.V., Reddy, Kakarla Raghava, Ravishankar, R., Sangeeta, M., Shetti, Nagaraj P., Reddy, Ch Venkata
• Format: Journal Article
• Language: English
• Published: Elsevier Ltd 01-01-2022
• Subjects: Doped ZnO nanoparticles; Environmental remediation; Green synthesis; Morphology; Photocatalysis; Toxic organic pollutants; Environmental remediation; Green synthesis; Toxic organic pollutants; Morphology; Photocatalysis; Doped ZnO nanoparticles
• ISSN: 0045-6535; 1879-1298
• DOI: 10.1016/j.chemosphere.2021.132081

In recent times, the synthesis of metal nanoparticles (NPs) using plant extracts has recently emerged as an intriguing issue in the field of nanoscience and nanobiotechnology, with numerous advantages over conventional physicochemical approaches. In the current study, ZnO NPs were synthesized from Synadium grantii leaf extricate with varying Cu-dopant concentrations. In order to the synthesis of the pure and Cu-doped ZnO NPs, zinc nitrate hexahydrate and copper nitrate trihydrate were used as a precursor in leaf extracts of the plant. XRD, TEM, FTIR, XPS, and PL measurements were carried out to examine the physical and optical properties of the synthesized samples. The photocatalytic studies of the prepared samples were studied using Methylene blue (MB), Indigo Carmine (IC), and Rhodamine B (RhB) organic pollutants. The wurtzite crystal structure of synthesized samples was confirmed by XRD and TEM analysis. Further, the presence of functional groups in the prepared samples was confirmed by FTIR analysis. XPS analysis confirmed that the binding energies of a host material and dopant ions. The emission peaks identified at 424, 446 and 573 nm are associated with the electron movement from the deep donor level, zinc interstitial to the zinc vacancy and oxygen vacancy. 3% and 5% Cu-doped samples exhibited superior photocatalytic activity for MB, IC, and RhB dyes. The green synthesized ZnO NPs showed enriched photocatalytic performance, signifying that bio-synthesis can be an outstanding approach to develop versatile and environmental products.
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•Pure and Cu-doped ZnO NPs have been synthesized by the green method.•As-prepared samples exhibit Wurtzite crystal structure of ZnO.•MB, IC, and RhB organic pollutants were used as model organic pollutants.•3% Cu-doped sample showed superior catalytic performance of MB and IC dyes.•In case of RhB dye, 5% Cu-doped sample showed superior photocatalytic performance.