Fabrication of reduced graphene oxide membranes for water desalination

• Published in: Journal of membrane science Vol. 572; pp. 12 - 19
• Main Authors: Huang, Hsin-Hui, Joshi, Rakesh K., De Silva, K. Kanishka H., Badam, Rajashekar, Yoshimura, Masamichi
• Format: Journal Article
• Language: English
• Published: Elsevier B.V 15-02-2019
• Subjects: Graphene; Hydrothermal reduction; Membranes; Reduced graphene oxide; Hydrothermal reduction; Membranes; Reduced graphene oxide; Graphene
• ISSN: 0376-7388; 1873-3123
• DOI: 10.1016/j.memsci.2018.10.085

Reduced graphene oxide (rGO) has huge potential for membrane applications owing to its appropriate interlayer spacing (0.34–0.37 nm) that enables it to block salt ions as small as Na+ with high precision. However, fabrication of uniform rGO membranes is a great challenge because of the loss of its polar functional groups during preparation from graphene oxide (GO). Although there have been several studies on GO membranes and a few on rGO for water purification, very few attempts to understand the role of oxygen-containing functional groups in successful rGO membrane formation. The present work deals with the investigation of the key factors and functional groups that govern membrane formation. This work also utilizes the facile approach of synthesizing reduced GO by environmentally viable hydrothermal reduction. Further characterizations show that the hydroxyl and carboxyl groups are principally responsible for the formation of uniform rGO membranes. The rGO (treated at 160°C for 2 h) membrane with a small amount of unreduced GO presented shows the lowest Na+/Cl- ion permeation with the highest membrane flux, which is suggested to be a potential candidate for water desalination.
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•Examination of reduced graphene oxide (rGO) membrane formability by reduction.•Uniform rGO membranes were formed at the partial reduction stage (GO/rGO coexist).•The presence of hydroxyl and carboxyl groups assists membrane formation.•The ion permeation and water transport are manipulated by degree of reduction.