Synthesis of mesostructured stishovite from FDU-12/carbon composite

• Published in: Microporous and mesoporous materials Vol. 187; pp. 145 - 149
• Main Authors: Stagno, V., Mandal, M., Yang, W., Ji, C., Fei, Y., Mao, H.-K., Landskron, K.
• Format: Journal Article
• Language: English
• Published: San Diego, CA Elsevier Inc 15-03-2014; Elsevier
• Subjects: Carbon; Chemistry; Colloidal state and disperse state; Exact sciences and technology; FDU-12; General and physical chemistry; Mesostructure; Porous materials; Small-angle X-ray diffraction; Solid-gas interface; Stishovite; Surface physical chemistry; Small-angle X-ray diffraction; Stishovite; Carbon; FDU-12; Mesostructure; Gas solid adsorption; Synthesis; Silicon oxides; X ray diffraction; Porous material; Composite material
• ISSN: 1387-1811; 1873-3093
• DOI: 10.1016/j.micromeso.2013.12.032

•Synthesis of mesostructured stishovite from FDU-12/carbon composite.•Mesostructured stishovite was synthesized at high pressure using multi-anvil apparatus.•We provide evidence for mechanism of crystallization of stishovite at much lower temperature than previous studies.
Nanocasting at high pressure has been recently proposed as a novel strategy for the synthesis of periodic mesoporous materials with crystalline walls. In this study we present results on the synthesis of mesostructured stishovite from mesostructured FDU-12/carbon composite precursor using the multi-anvil press. Results from quenched experiments performed at a pressure of 14GPa indicate that a minimum temperature of 500°C is needed to crystallize stishovite from the amorphous silica precursor with a preserved mesostructure. Transmission electron microscopy combined with small angle X-ray scattering measurements confirmed the mesostructure of synthetic stishovite having carbon-filled pores with a diameter of ∼19nm similar to the pore size of the FDU-12 precursor. Calcination of the stishovite/carbon composite at 450°C in air at ambient condition leads to amorphization of the stishovite. Our results show that mesostructure materials can be synthesized at very high pressures without loss or critical modification of the mesostructure.