Synthesis and Characterization of Cerium(IV) Metallocenes

Synthesis and Characterization of Cerium(IV) Metallocenes

By applying a salt metathesis approach between Ce(OtBu3)2(NO3)2(THF)2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadi...

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Bibliographic Details
Published in:Inorganics Vol. 3; no. 4; pp. 589 - 596
Main Authors: Sutton, Andrew, Clark, David, Scott, Brian, Gordon, John
Format: Journal Article
Language:English
Published: Basel MDPI AG 01-12-2015
MDPI
Subjects:
cerium
Cerium oxides
Chemical synthesis
Crystal structure
cyclopentadiene
Inorganic chemistry
INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
organometallic
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Summary:By applying a salt metathesis approach between Ce(OtBu3)2(NO3)2(THF)2 and the potassium salts of mono- and ditrimethylsilyl substituted cyclopentadienes, we were able to isolate two new Ce(IV) metallocenes, including to the best of our knowledge, the first structurally characterized bis-cyclopentadiene Ce(IV) compound.
Bibliography:USDOE Laboratory Directed Research and Development (LDRD) Program
LA-UR-15-29339
AC52-06NA25396
ISSN:2304-6740
2304-6740
DOI:10.3390/inorganics3040589