Experimental determination of pesticide processing factors during extraction of seed oils

• Published in: Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & risk assessment Vol. 37; no. 9; pp. 1491 - 1502
• Main Authors: Lacoste, Florence, Carré, Patrick, Dauguet, Sylvie, Petisca, Catarina, Campos, Fernando, Ribera, Daniel, Roïz, Julie
• Format: Journal Article
• Language: English
• Published: Abingdon Taylor & Francis 01-09-2020; Taylor & Francis Ltd
• Subjects: chlorpyrifos-methyl; Crude oil; deltamethrin; Dilution; Fats; Food processing; Food processing industry; Fungicides; Metalaxyl; metalaxyl-M; Oils & fats; Pesticide residues; Pesticides; pilot scale trials; pirimiphos-methyl; Processed foods; processing factors; procymidone; rapeseed oil; Raw materials; Reliability analysis; Reliability aspects; Residues; Solvent extraction; Vegetable oil; Vegetable oils; Vegetables
• ISSN: 1944-0049; 1944-0057
• DOI: 10.1080/19440049.2020.1778188

Processing Factors (PFs) reflect the concentration or dilution of pesticide residues resulting from food processing. PFs are key elements to demonstrate the compliance of processed foods with Maximum residue levels (MRLs) as set by Regulation 396/2005. While efforts have been made by the European Food Safety Authority (EFSA) and by national authorities to compile PFs from processing studies, such PFs are not available for all pesticides/processed product combinations. The EU vegetable oil and proteinmeal industry association (FEDIOL) has therefore developed a theoretical approach to approximate MRLs in crude vegetable oils and fats, based on the partition coefficient (log P
ow
) of the pesticides and on the oil content of the raw materials. To substantiate this approach, a pilot-scale processing study was initiated with rapeseeds spiked with selected pesticides and the experimental PFs for these pesticides determined. The aims of this study were (i) to study the reliability of pilot-scale conditions for PF determination and (ii) to assess the experimental PFs obtained in comparison to the theoretical PFs proposed by FEDIOL. This study demonstrated that production yields obtained for crude oil and meal in this processing study are similar to those in industrial processes even if differences were observed in the individual production steps (mechanical or solvent extraction steps). The experimental PFs obtained confirmed that the chosen fat-soluble pesticides did concentrate in the oil fraction. For metalaxyl-M having a log P
ow
lower than 3, a partitioning between the oil and the meal was observed, as expected. By comparing the experimental PFs and theoretical PFs, it can be concluded that the FEDIOL approach can be recommended as a suitable tool when PFs derived from specific processing studies are missing. Similar studies on pesticides with wider ranges of log P
ow
are required in order to complete our conclusions on default PFs for vegetable oils.