Convenient Access to Monosilicon Epoxides with Pentacoordinate Silicon

Convenient Access to Monosilicon Epoxides with Pentacoordinate Silicon

From intermediate to stable molecule: Stable monosilicon epoxides with pentacoordinate silicon were prepared for the first time by [2+1] cycloaddition reactions of Lewis base stabilized chlorosilylenes with ketones. Molecular structures of these compounds with SiOC three‐membered rings were establis...

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Bibliographic Details
Published in:Angewandte Chemie (International ed.) Vol. 49; no. 23; pp. 3952 - 3955
Main Authors: Ghadwal, Rajendra S, Sen, Sakya S, Roesky, Herbert W, Granitzka, Markus, Kratzert, Daniel, Merkel, Sebastian, Stalke, Dietmar
Format: Journal Article
Language:English
Published: Weinheim Wiley-VCH Verlag 25-05-2010
WILEY-VCH Verlag
WILEY‐VCH Verlag
Subjects:
carbene ligands
cycloaddition
heterocycles
silicon
small-ring systems
Online Access:Get full text
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Summary:From intermediate to stable molecule: Stable monosilicon epoxides with pentacoordinate silicon were prepared for the first time by [2+1] cycloaddition reactions of Lewis base stabilized chlorosilylenes with ketones. Molecular structures of these compounds with SiOC three‐membered rings were established by X‐ray diffraction studies (e.g., see picture; N blue, O red, Cl green).
Bibliography:http://dx.doi.org/10.1002/anie.201000835
ArticleID:ANIE201000835
ark:/67375/WNG-SH9DH32Z-6
Deutsche Forschungsgemeinschaft
Support of the Deutsche Forschungsgemeinschaft is highly acknowledged.
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ObjectType-Article-1
SourceType-Scholarly Journals-1
ObjectType-Feature-2
content type line 23
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201000835