Erosion-wear and intergranular corrosion resistance properties of AISI 304L austenitic stainless steel after low-temperature plasma nitriding

• Published in: Journal of alloys and compounds Vol. 698; pp. 1094 - 1101
• Main Authors: Qin, Xujuan, Guo, Xianglong, Lu, Junqiang, Chen, Liangyu, Qin, Jining, Lu, Weijie
• Format: Journal Article
• Language: English
• Published: Lausanne Elsevier B.V 25-03-2017; Elsevier BV
• Subjects: Activation; Austenitic stainless steel; Austenitic stainless steels; Corrosion resistant steels; Corrosive wear; Erosion resistance; Erosion-wear; Expanded austenitic phase; Impact angle; Intergranular corrosion; Ion nitriding; Low temperature; Low-temperature plasma nitriding; Microhardness; Microstructure; Nitrides; Transmission electron microscopy; Wear resistance; Erosion-wear; Austenitic stainless steel; Expanded austenitic phase; Intergranular corrosion; Low-temperature plasma nitriding
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2016.12.164

In this paper, AISI 304L austenitic stainless steel has been subjected to plasma nitriding at 673 and 681 K lasted for 6, 18, 24, and 36 h. The morphology, microhardness, phase, and microstructure evolution of the nitrided layer were studied. Not only an expanded austenitic phase (γN) but also Cr-nitrides were formed in the nitrided layer. Transmission Electron Microscopy (TEM) study showed the formation of amorphous and nanocrystalline phases in the surface layers of the samples. The erosion-wear and intergranular corrosion (IGC) resistance behaviors of the nitrided samples were studied in detail. As compared to the non-nitrided sample, the erosion-wear resistance of the nitrided layer at normal impact angle doubles after nitriding at 673 K for 6 h, as a result of the formation of γN phase. Degree of sensitization (DOS) of IGC is gradually enhanced with the increase of nitriding time as indicated by a double loop electrochemical potentiokinetic reactivation (DL-EPR) measurement. This is assigned to the nanostructuring and to the Cr-depletion in the areas adjacent to the Cr-nitrides.
•Amorphous and nanocrystalline phases were detected on the top of the nitrided layer by TEM.•The DOS of IGC was analyzed in detail by DL-EPR measurement.•Erosion-wear resistance of the sample nitrided at 673 K for 6 h was doubly enhanced.•The enhancement of the surface microhardness (673 K-36 h) reached up to ∼ 6 times.