Cobalt and iron supported on carbon nanofibers as catalysts for Fischer–Tropsch synthesis

• Published in: Fuel processing technology Vol. 128; pp. 417 - 424
• Main Authors: Díaz, José Antonio, Akhavan, Hasti, Romero, Amaya, Garcia-Minguillan, Alba María, Romero, Rubí, Giroir-Fendler, A., Valverde, Jose Luis
• Format: Journal Article
• Language: English
• Published: Amsterdam Elsevier B.V 01-12-2014; Elsevier
• Subjects: Applied sciences; Bimetallic catalysts; Bimetals; Carbon monoxide; Carbon nanofibers; Catalysis; Catalysts; Chemical Sciences; Cobalt; Conversion; Energy; Environment and Society; Environmental Sciences; Exact sciences and technology; Fischer–Tropsch; Fuel processing. Carbochemistry and petrochemistry; Fuels; Gas processing; Iron; Nanofibers; Fischer–Tropsch; Carbon nanofibers; Bimetallic catalysts; Iron; Cobalt; Mixed catalyst; Molecular structure; Fischer Tropsch synthesis; Temperature programmed reduction; Transition metal; Nanostructure; X ray; X ray diffraction; Supported catalyst; Characterization; Fischer-Tropsch; Photoelectron spectrometry; Catalyst activity; Carbon fiber; Crystalline structure
• ISSN: 0378-3820; 1873-7188
• DOI: 10.1016/j.fuproc.2014.08.005

Cobalt and/or iron supported on carbon nanofibers were prepared and used as monometallic or bimetallic catalysts for Fischer–Tropsch synthesis at 523K and 20bar. Catalysts were characterized by ICP, N2 adsorption–desorption, TPR, XRD and XPS. Characterization results revealed that cobalt and iron had a synergetic effect: cobalt particles were better dispersed in presence of iron, and the latter was reduced to Fe0 in a higher extent due to the presence of the former. Catalytic results revealed that cobalt content played an important role in the catalytic conversion of CO. This way, the higher the content in cobalt, the higher the CO conversions were observed. Thus, sample 15Co/CNF presented the highest CO conversion. However, the presence of iron in bimetallic catalysts avoided an excessive production of CH4. The bimetallic sample with the highest Co loading (10Co5Fe/CNF) was the most active catalyst for the FTS reaction, because it led to the highest yield of long-chained hydrocarbons.
•Cobalt particles were better dispersed in presence of iron.•Iron was reduced in a higher extent in presence of cobalt.•The presence of iron in a Co:Fe catalyst limited the undesired CH4 production.