Sulfated zirconia and tungstated zirconia as effective supports for Pd-based SCR catalysts

• Published in: Catalysis today Vol. 62; no. 2; pp. 159 - 165
• Main Authors: Chin, Ya-Huei, Alvarez, Walter E, Resasco, Daniel E
• Format: Journal Article Conference Proceeding
• Language: English
• Published: Amsterdam Elsevier B.V 01-11-2000; Elsevier Science
• Subjects: Catalysis; Catalysts: preparations and properties; Chemistry; Exact sciences and technology; General and physical chemistry; SCR catalyst; Sulfated zirconia; Theory of reactions, general kinetics. Catalysis. Nomenclature, chemical documentation, computer chemistry; Tungstated zirconia; Tungstated zirconia; SCR catalyst; Sulfated zirconia; Water; Methane; Catalytic reaction; Deactivation; Hydrocarbon; Transition metal; Palladium; Selectivity; Experimental study; Sulfates; Supported catalyst; Sulfur dioxide; Chemical reduction; Heterogeneous catalysis; Tungsten oxide; Zirconium oxide; Nitric oxide; Preparation; Platinoid; Catalyst activity; Modified material
• ISSN: 0920-5861; 1873-4308
• DOI: 10.1016/S0920-5861(00)00417-X

It is now well established that even though Pd supported on acidic zeolites is highly selective for CH
4-SCR, zeolitic structures are susceptible to dealumination under hydrothermal environments. In this contribution, we have investigated the ability of non-zeolitic acidic materials to promote the SCR selectivity and stability in the presence of H
2O and SO
2. The results of catalytic activity measurements and characterization tests indicate that sulfated zirconia and tungstated zirconia are supports as effective as the zeolites for the promotion of SCR activity. The high SCR activity of these catalysts can be ascribed to the formation of isolated Pd
2+ ions on acid sites. It is proposed that the stabilization of Pd
2+ on these supports is similar to the stabilization previously reported for acidic zeolites. The remarkable characteristic of these Pd catalysts supported on sulfated zirconia and tungstated zirconia is that when they were tested over a 40
h reaction period in the presence of H
2O and SO
2, they appeared to be significantly more resistant than zeolite-based catalysts.