Influence of incorporation of starch nanoparticles in PBAT/TPS composite films

• Published in: Polymer international Vol. 65; no. 8; pp. 938 - 945
• Main Authors: González Seligra, Paula, Eloy Moura, Lídia, Famá, Lucia, Druzian, Janice Izabel, Goyanes, Silvia
• Format: Journal Article
• Language: English
• Published: Chichester, UK John Wiley & Sons, Ltd 01-08-2016; Wiley Subscription Services, Inc
• Subjects: biodegradability; Breaking; Compatibility; Extrusion; Hydroxyl groups; Nanoparticles; PBAT; Segments; starch nanoparticles; Starches; thermal properties; Thermoplastic resins; TPS
• ISSN: 0959-8103; 1097-0126
• DOI: 10.1002/pi.5127

The presence of starch nanoparticles (NP) during composite extrusion leads to a higher degree of starch gelatinization, improving starch compatibility with PBAT.
Films of PBAT/TPS (poly(butylene adipate‐co‐terephthalate)/thermoplastic starch) (starch plasticized with glycerol containing citric and stearic acids) without and with 0.6 wt% starch nanoparticles were produced by extrusion. The presence of nanoparticles during the extrusion process led to a higher degree of starch gelatinization improving starch compatibility with PBAT. Nanoparticles modified the interaction between the different components of the PBAT/TPS composite. The hydroxyl groups of the starch nanoparticles interacted with starch amylose by means of hydrogen bonds. In addition, nanoparticles modified the structure of the PBAT rigid segment (BT): a shift of Tm of BT toward lower temperatures and a slight shift of the relaxation of the BT segment to higher temperatures were observed. The incorporation of nanoparticles also had a reinforcing effect on the PBAT/TPS matrix. The composite presented slight increases of Young's modulus (E) and stress at break (σb) without affecting the strain at break (ϵb). The rate of biodegradability was improved with the use of starch nanoparticles. The composite showed faster deterioration than the matrix, showing the first changes in its tonality and breakdowns at only 6 days of burial in compost. © 2016 Society of Chemical Industry